High Temperature Materials

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Prof. Dr.-Ing. Michael Schütze

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DECHEMA Research Institute > Materials > High Temperature Materials > Publications

Publications - Prof. Dr.-Ing. Michael Schütze

Scientific Papers

Corrosion and Creep/LCF
Mechanical Properties of Oxide Scales
Ni-base Alloys and Coatings for Gas Turbines
Thermal Barrier Coatings
Coatings for Thermal Power Stations
Materials and Coatings for Sulfidizing Environments
Materials and Coatings for Carburizing and Metal Dusting Environments
Materials and Coatings for Halogen-containing Environments
Titanium Aluminides
Silicides and Si-based Ceramics
Materials in Water Vapour Containing Enviroments
Heat-Resistant Steels
Investigation Techniques
Corrosion and Protection in Liquid Media
Role of Microstructure
Mechanical High Temperature Properties without Corrosion
Nanotechnology
Reviews

Books

Contributions to Newspapers

Scientific Papers

Corrosion and Creep/LCF

K.-H. Döhle, A. Rahmel, M. Schmidt, M. Schütze: Two Different Test Rigs for Creep Experiments in Aggressive Environments; in "Corrosion and Mechanical Stress at High Temperatures", Eds. V. Guttmann, M. Merz, Applied Science Publishers, London (1981) 441
U. Bruch, K. Döhle, J. Pütz, A. Rahmel, M. Schütze, K.D. Schuhmacher: Comparison of the Corrosion Behaviour of Different High Temperature Alloys with and without Superimposed Creep Deformation in an Artificial Steam Reformer Atmosphere; in "Metallic Corrosion 1984", Vol. III, National Research Council Canada, Toronto (1984) 325
M. Schütze: The Influence of High Temperature Corrosion on Creep and Fracture Behaviour of Heat Resistant Steels; in "Creep and Fracture of Engineering Materials and Structures", Eds. B. Wilshire, D. Owen, Pineridge Press, Swansea (1984) 801
B. Ilschner, M. Schütze: Interaction Between Oxidation (Sulfidation, Carburization) and Creep; Oxidation of Metals 23 (1985) 287-292
J. Barbehön, A. Rahmel, M. Schütze: Behaviour of Alloy 800 H under Cyclic Deformation and Superimposed Oxidation; in "High Temperature Alloys for Gas Turbines and Other Applications 1986", Eds. W. Betz et al. D. Reidel Publishing Company, Dordrecht (1986) 1267
V. Guttmann, M. Schütze: Interactions of Corrosion and Mechanical Properties; in "High Temperature Alloys for Gas Turbines and Other Applications 1986", Eds. W. Betz et al., D. Reidel Publishing Company, Dordrecht (1986) 293
J. Barbehön, A. Rahmel, M. Schütze: Investigations on the Interaction of LCF and Oxidation; in "Low Cycle Fatigue and Elasto-Plastic Behaviour of Materials", Ed. K.-T. Rie, Elsevier Appl. Sci., London (1987) 371
M. Welker, M. Schütze, A. Rahmel: Untersuchungen zur Wechselwirkung zwischen Korrosion und Rißfortschritt bei Hochtemperatur-Kriechverformung; in "Bruchvorgänge 1987", DVM, Berlin (1987) 345
M. Schütze: Anrißentstehung und Anrißwachstum unter korrosiven Bedingungen bei hohen Temperaturen; in "Korrosion und Bruch", DVM, Berlin (1988) 279
M. Schütze: Concept for the Assessment of the Contribution to Damage by the Interaction of High Temperature Corrosion and Mechanical Stresses; Proc. Conf. 9th Europ. Congr. Corr., Vol. I, Europ. Federation of Corrosion (1989) FU-202
M. Schütze: The Role of the Interaction of Corrosion and Mechanical Factors for Degradation of Materials; Materials Science and Engineering A 121 (1989) 563
M. Welker, A. Rahmel, M. Schütze: Oxidation and Nitridation of Alloy 800 H at a Growing Creep Crack and for Unstressed Samples; Metallurgical Transactions A 20 (1989) 1541
M. Welker, A. Rahmel, M. Schütze: Investigations on the Influence of Internal Nitridation on Creep Crack Growth in Alloy 800 H; Metallurgical Transactions A 20 (1989) 1553
M. Schütze, H. Fellmann: Investigations on Creep Crack Growth in Air and Oxygen + SO₂; in "High Temperature Materials for Power Engineering 1990", Eds. E. Bachelet et al., Kluwer Academic Publ., Dordrecht (1990) 199
M. Schütze: The Interaction of High Temperature Corrosion and Mechanical Factors; in "High Temperature Corrosion and Protection", Eds. H. Guan et al., Liaoning Science and Technology Publ., Shenyang (1991) 359
M. Schütze, H. Fellmann, B. Glaser: Kriechrißwachstum in Luft und SO₂-haltiger Umgebung; Materialprüfung 33 (1991) 11
M. Schütze, H. Fellmann, B. Glaser: Untersuchungen zum Kriechrißwachstum in Luft und O₂-SO₂; in "Bruchvorgänge 1991", DVM, Berlin (1991) 357
M. Welker, H. Fellmann, B. Glaser, M. Schütze: Creep Crack Growth of Materials for the Chemical and Petrochemical Industries; in "Heat-Resistant Materials", Eds. K. Natesan, D.J. Tillack, ASM International, Ohio (1991) 477
M. Schütze, H. Fellmann: Corrosion Processes at Growing Creep Cracks; in "Corrosion - Deformation Interactions", Eds. T. Magnin, J.M. Gras, Les Editions de Physique, Les Ulis (1992) 565-576
M. Schütze, B. Glaser: The Role of Environmental Effects for the Mechanical Behaviour of Materials at High Temperatures; in "Aspects of High Temperature Deformation and Fracture in Crystalline Materials", Eds. Y. Hosoi et al., The Japan Institute of Metals, Sendai (1993) 561-567
M. Schütze: Hochtemperaturkorrosion und mechanische Beanspruchung; in "Korrosion verstehen - Korrosionsschäden vermeiden", Eds. H. Gräfen, A. Rahmel, Verlag Irene Kuron, Bonn (1994) 402-410
M. Schütze, B. Glaser: The Influence of Cl-Containing Atmospheres on Creep Crack Growth at 800ºC; in "Heat-Resistant Materials II", Eds. K. Natesan et al., ASM International, Materials Park (Ohio) (1995) 343-351
M. Schütze, V. Guttmann, M.F. Stroosnijder: Simultaneous Corrosion and Mechanical or Thermal Stresses; in "Guidelines for Methods of Testing and Research in High Temperature Corrosion", Eds. H.J. Grabke, D.B. Meadowcroft, European Federation of Corrosion Publications No. 14, The Institute of Materials, London (1995) 104-120
J.P.T. Vossen, M. Schütze: Limits for the Recovery of Chromium Oxide Scales on Heat-resistant Stainless Steels in Air With and Without Superimposed Mechanical Load at 650°C; Proc. Int. Conf. Corrosion-Deformation Interactions (CDI), Vol. IV, Paper P 40 Centre Français de l'Anticorrosion/Société de Chimie Industrielle, Paris (1996)
A. Jeutter, M. Schütze: The Influence of HCl-containing Atmospheres on High Temperature Corrosion of Coated and Uncoated Nickel-Base Superalloys under Complex Loading Conditions; Proc. EUROMAT 97, Vol. 1, Netherlands Society for Materials Science, Zwijndrecht/NL (1997) 223-226
M. Schütze: Werkstoffverhalten bei Wechselwirkung von Hochtemperaturkorrosion und mechanischer Belastung; in "Hochtemperaturkorrosion in der Prozeßtechnik", TAW-Verlag, Wuppertal (1998) 1-23
M. Schütze, A. Jeutter: High temperature corrosion resistance of gas turbine materials and coatings under the influence of Cl-contaminations; in "Materials for advanced power engineering 1998", Eds. J. Lecomte-Beckers et al., Reihe Energietechnik, Vol. 5, Forschungszentrum Jülich (1998) 1543-1552
A. Jeutter, M. Schütze: The Role of HCl Impurities in the Environment and Y for the High Temperature Corrosion of CoNiCrAl(Y)-Coatings on a Ni-base Superalloy under Complex Loading Conditions; Materials at High Temperatures 16 (1999) 71-86
A. Zeller, F. Dettenwanger, M. Schütze: Influence of Water Vapor on the Creep Behaviour of TiAl; in "Gamma Titanium Aluminides 1999", Eds. Y.-W. Kim et al., TMS, Warrendale (1999) 761-768
M. Schütze: Hochtemperaturkorrosion bei gleichzeitiger mechanischer Beanspruchung; in "Korrosion und Korrosionsschutz", Ed. E. Kunze, Wiley-VCH, Weinheim (2001) 648-687
A. Zeller, F. Dettenwanger, M. Schütze: Influence of water vapour on the creep and fatigue properties of TiAl; Intermetallics 10 (2002) 33-57

Mechanical Properties of Oxide Scales

M. Schütze, A. Rahmel: Das Verhalten von Oxidschichten unter mechanischer Belastung; in "Aufbau von Oxidschichten auf Hochtemperaturwerkstoffen und ihre technische Bedeutung", Ed. A. Rahmel, Deutsche Gesellschaft für Metallkunde, Oberursel (1983) 245
M. Schütze, A. Rahmel: Influence of Constant Strain Rates on Growth and Cracking Behavior of Oxide Scales and on Internal Corrosion of a 18Cr-0.8Al-1.5Si Steel; in "High Temperature Corrosion", Ed. R. Rapp, NACE, Houston (1983) 421
M. Schütze, A. Rahmel: Observations on the Cracking Behaviour of Oxide Scales During Creep of the Base Metal and on Creep Enhanced Internal Corrosion; in "Corrosion Resistant Materials for Coal Conversion Systems", Eds. D. Meadowcroft, M. Manning, Applied Science Publ, London (1983) 439
M. Schütze: Deformation and Cracking Behavior of Protective Oxide Scales on Heat-Resistant Steels under Tensile Strain; Oxidation of Metals 24 (1985) 199
M. Schütze: The Healing Behavior of Protective Oxide Scales on Heat-Resistant Steels after Cracking under Tensile Strain; Oxidation of Metals 25 (1986) 409
M. Schütze: Computer Simulation of Oxide Scale Cracking/Healing Processes under Substrate Creep at High Temperatures and Comparison of the Results to Experimental Data; Materials and Corrosion 38 (1987) 637
M. Schütze: The Limits to the Protective Effect of Oxide Scales on High Temperature Materials Which are Subjected to Strain; in "High Temperature Alloys - Their Exploitable Potential", Elsevier Applied Science, London (1987) 79
J. Barbehön, A. Rahmel, M. Schütze: Behavior of the Scale on a 9.5Cr Steel under Cyclical Deformation of the Base Metal; Oxidation of Metals 30 (1988) 85
M. Schütze: Stresses and Decohesion of Oxide Scales; Materials Science and Technology 4 (1988) 407
W. Christl, A. Rahmel, M. Schütze: Behavior of Oxide Scales on 2.25Cr-1Mo Steel During Thermal Cycling. I. Scales Formed in Oxygen and Air; Oxidation of Metals 31 (1989) 1
W. Christl, A. Rahmel, M. Schütze: Behavior of Oxide Scales on 2.25Cr-1Mo Steel During Thermal Cycling. II. Scales Grown in Water Vapor; Oxidation of Metals 31 (1989) 35
M. Schütze: Plasticity of Protective Oxide Scales; Materials Science and Technology 6 (1990) 32
I. Küppenbender, M. Schütze: Deformation and Cracking Behaviour of NiO Scales on Nickel; Proc. EUROCORR '91, GTE, Budapest (1991) 342
M. Schütze: Assessment of the Limits to the Protective Effect of Oxide Scales in High Temperature Technology, Set by Deformation of the Substrate Material; Int. J. Pres. Ves. Pip. 47 (1991) 293
A. Rahmel, M. Schütze: Mechanical Aspects of the Rare-Earth Effect; Oxidation of Metals 38 (1992) 255
M. Schütze: Failure of Oxide Scales on Advanced Materials Due to the Presence of Stresses; in "High Temperature Corrosion of Advanced Materials and Protective Coatings", Eds. Y. Saito et al., Elsevier, Amsterdam (1992) 39
M. Schütze: Fundamental Aspects of High Temperature Corrosion and The Role of Surface Layers in Corrosion-Deformation Interactions; in "Corrosion-Deformation Interactions", Eds. T. Magnin, J.M. Gras, Les Editions de Physique, Les Ulis (1992) 703
M. Schütze: Mechanical Aspects of High-Temperature Oxidation; Corrosion Science 35 (1993) 955-963
M. Walter, M. Schütze, A. Rahmel: Behavior of Oxide Scales on 12Cr-1Mo Steel During Thermal Cycling; Oxidation of Metals 39 (1993) 389-410
M. Walter, M. Schütze, A. Rahmel: Behavior of Oxide Scales on Alloy 800 H and HK 40 During Thermal Cycling; Oxidation of Metals 40 (1993) 37
A.M. Huntz, M. Schütze: Stresses Generated During Oxidation Sequences and High Temperature Fracture; Mater. High Temp. 12 (1994) 151-161
I. Küppenbender, M. Schütze: The Deformation Behavior of NiO Scales on Ni in Argon and Air at Temperatures from 20 to 800ºC With Respect to the Relief of Growth Stresses; Oxidation of Metals 42 (1994) 109-144
S.R.J. Saunders, M.M. Nagl, M. Schütze: Measurement Methods for the Determination of Fracture Strain; Mater. High Temp. 12 (1994) 103-109
M. Schütze: An Approach to a Global Model of the Mechanical Behaviour of Oxide Scales; Mater. High Temp. 12 (1994) 237-247
M. Schütze, M. Schmitz: The Oxidation Behaviour of Titanium Aluminide under the Effect of Mechanical Stresses; Trans. Mat. Res. Soc. Jpn. 14A (1994) 219-224
M. Schütze: Mechanical Properties of Oxide Scales; Oxidation of Metals 44 (1995) 29-61
M. Schütze, M. Schmitz-Niederau: Interaction of Mechanical Loading and Oxidation at 900ºC for TiAl; in "Gamma Titanium Aluminides", Eds. Y.-W. Kim, R. Wagner, M. Yamaguchi, TMS Warrendale (1995) 83-92
M. Schütze, J.R. Nicholls: Behavior of Scales Under Mechanical Loading; Oxidation of Metals 45 (1996) 605-613
C. Bruns, M. Schütze: Messung der Haftfestigkeit von Deckschichten mittels Schallemissionsanalyse; Berichtsband 58 "Statusberichte zur Entwicklung und Anwendung der Schallemissionsanalyse", Deutsche Gesellschaft für Zerstörungsfreie Prüfung e.V. Berlin (1997) 235-237
M. Schütze, C. Bruns: Stresses and Adhesion of Surface Scales; in "Corrosion-Deformation Interactions", Ed. T. Magnin, EFC-Publ. No. 21, The Institute of Materials, London (1997) 308-318
M. Schütze, W. Przybilla: The role of stresses in oxidation and shape stability; in "Metal-supported automotive catalytic converters", Ed. H. Bode, Werkstoff-Informationsgesellschaft, Frankfurt am Main (1997) 163-177
W. Przybilla, M. Schütze: Monitoring stress relaxation processes in growing oxide scales via acoustic emission analysis; Proc. of the 23rd Europ. Conf. on Acoustic Emission Testing, Ed. P. Tscheliesnig, TÜV Österreich, Wien (1998) 74-79
M. Schütze: Mechanical Interactions in Oxide Scales; in "High Temperature Corrosion and Materials Chemistry", Eds. P.Y. Hou et al., The Electrochem. Soc., Pennington (1998) 1-17
M. Schmitz-Niederau, M. Schütze: Cracking and Healing of Oxide Scales on Ti-Al Alloys at 900°C; Oxidation of Metals 52 (1999) 241-276
C. Bruns, M. Schütze: Investigation of the Mechanical Properties of Oxide Scales on Nickel and TiAl; Oxidation of Metals 55 (2001) 35-68
M. Schütze: Hochtemperaturoxidation unter zyklischer Temperaturbeanspruchung; in "Korrosion und Korrosionsschutz", Ed. E. Kunze, Wiley-VCH, Weinheim (2001) 687-700
M. Schütze, S. Ito, W. Przybilla, H. Echsler, C. Bruns: Test Methods and Data on the Mechanical Properties of Protective Oxide Scales; Materials at High Temperatures 18 (2001) 39-50
W. Przybilla, M. Schütze: Role of growth stresses on the structure of oxide scales on nickel at 800 and 900°C; Oxidation of Metals 58 (2002) 103-145
W. Przybilla, M. Schütze: Growth stresses in the oxide scales on TiAl alloys at 800 and 900°C; Oxidation of Metals 58 (2002) 337-359
H. Echsler, M. Schütze, S. Ito: Deformation and fracture properties of oxide scales on mild steel at elevated temperatures; Current Advances in Materials and Processes (ISIJ) 16 (2003) 1329-1332
M. Schütze: Stress controlled mechanisms in the oxidation of metallic alloys; Proc. Int. Symp. "Corrosion Science in the 21st Century", UMIST, Manchester 2003 (CD), Journal of Corrosion Science and Engineering 6 (2003) 1-31
G. Wright, M. Schütze, S.R. Paterson, P.F. Tortorelli, R.B. Dooley: Progress in prediction and control of scale exfoliation on superheater and reheater alloys; Proc. EPRI International Conference on Boiler Tube and HRSG Tube Failures and Inspections, San Diego (2004)
M. Schütze: Modelling oxide scale fracture; Materials at High Temperatures 22 (2005) 147-154
M. Schütze, M. Malessa, D. Renusch, P.F. Tortorelli, I.G. Wright, R.B. Dooley: Mechanical Properties and Adherence of Oxide Scales; Materials Science Forum 522-523 (2006) 393
M. Schütze: Mechanical Properties of Oxide Scales as a Key Issue for Oxidation Resistance; Current Topics on High Temperature Materials 48 (2007) 301-313
I.G. Wright, M. Schütze, P.F. Tortorelli, R.B. Dooley: Towards improved prediction of scale exfoliation from steam tubes; Materials at High Temperatures 24 (2007) 265-274
M. Schütze, I. Wright, P. Tortorelli: Recent Advances in the quantitative characterisation of mechanical scale failure; J. Chinese Society for Corrosion and Protection 29 (2009) 313
M. Schütze, P.F. Tortorelli, I.G. Wright: Development of a comprehensive oxide scale failure diagram; Oxidation of Metals 73 (2010) 389-418

Ni-base Alloys and Coatings for Gas Turbines

B. Reppich, H. Bügler, R. Leistner, M. Schütze: Application of the Microstructural Concept of Creep and Rupture Life Time to a γ'-Precipitating Ni-Base Alloy I. Yielding and Creep Behaviour; in "Creep and Fracture of Engineering Materials and Structures", Eds. B. Wilshire & D. Owen, Pineridge Press, Swansea (1984) 279
M. Göbel, A. Rahmel, M. Schütze: The Isothermal and Cyclic Oxidation Behaviour of Single-Crystal Nickel Base Superalloys in Air Between 800-1150ºC; in "High Temperature Materials for Power Engineering 1990", Eds. E. Bachelet et al., Kluwer Academic Publ., Dordrecht (1990) 1225
M. Göbel, A. Rahmel, M. Schütze: High Temperature Oxidation of Single-Crystal Superalloys; Proc. Eurocorr '91, GTE, Budapest (1991) 269
M. Göbel, A. Rahmel, M. Schütze: The Isothermal-Oxidation Behavior of Several Nickel-Base Single-Crystal Superalloys With and Without Coatings; Oxidation of Metals 39 (1993) 231
M. Göbel, A. Rahmel, M. Schütze: The Cyclic-Oxidation Behavior of Several Nickel-Base Single-Crystal Superalloys Without and With Coatings; Oxidation of Metals 41 (1994) 271-300
M. Göbel, A. Rahmel, M. Schütze, M. Schorr, W.T. Wu: Interdiffusion Between the Platinum-Modified Aluminide coating RT22 and Nickel-based Single-Crystal Superalloys at 1000 and 1200ºC; Mater. High Temp. 12 (1994) 301-309
T. Link, A. Rahmel, M. Schütze: The Influence of Gaseous Impurities in Air on the High Temperature Corrosion of Coated and Uncoated Nickel-based Superalloys; Materials at High Temperatures 13 (1995) 55-66
A. Jeutter, M. Schütze: The Influence of HCl-containing Atmospheres on High Temperature Corrosion of Coated and Uncoated Nickel-Base Superalloys under Complex Loading Conditions; Proc. EUROMAT 97, Vol. 1, Netherlands Society for Materials Science, Zwijndrecht/NL (1997) 223-226
M. Schütze, A. Jeutter: High temperature corrosion resistance of gas turbine materials and coatings under the influence of Cl-contaminations; in "Materials for advanced power engineering 1998", Eds. J. Lecomte-Beckers et al., Series Energietechnik, Vol. 5, Forschungszentrum Jülich (1998) 1543-1552
A. Jeutter, M. Schütze: The Role of HCl Impurities in the Environment and Y for the High Temperature Corrosion of CoNiCrAl(Y)-Coatings on a Ni-base Superalloy under Complex Loading Conditions; Materials at High Temperatures 16 (1999) 71-86
A. Littner, M. Schütze: The cyclic oxidation behaviour of several new aluminide and platinum aluminide diffusion coatings at 1150°C; Proc. Int. Symp. "Corrosion Science in the 21st Century", UMIST, Manchester 2003 (CD), The Journal of Corrosion Science and Engineering, Vol. 6 (2003)
E. Berghof-Hasselbächer, A. Littner, M. Schütze, M. Schorr, P. Gawenda: Charakterisierung von Al- und PtAl-Diffusionsbeschichtungen auf Ni-Basis-Superlegierungen; Sonderbände der Praktischen Metallographie 35 (2004) 325-336
K. Aleksandrov, M. Schütze: Depletion sensor for protective high temperature coatings; Proc. EUROCORR 2009 (CD), Nice/F (2009)
E. Berghof-Hasselbächer, P.J. Masset, D. Texier, G. Schmidt, P. Gawenda, M. Jusek, M. Schütze: Mikrostrukturen von NiAl_(1-x)Hf_(x)-Legierungen (x=0…0,2); Sonderbände der Praktischen Metallographie 41 (2009) 113-119
I. Teliban, C. Thede, S. Chemnitz, C. Bechtold, W.J. Quadakkers, M. Schütze, E. Quandt: Magnetic moment investigation by frequency mixing techniques; Review of Scientific Instruments 80 (2009) 115106
H.-E. Zschau, P.J. Masset, D. Renusch, M. Schütze: Thermodynamical Considerations for applying the Halogen Effect to Ni-Base Superalloys; Proc. TMS Spring Meeting, San Francisco/USA (2009) 149-156
H.-E. Zschau, D. Renusch, P.J. Masset, M. Schütze: A new concept of oxidation protection of Ni-base alloys by using the halogen effect; Materials at High Temperatures 26 (2009) 85-89
H.-E. Zschau, D. Renusch, P.J. Masset, M. Schütze: The halogen effect for Ni-base alloys - a new method for increasing the oxidation protection at high temperatures; Nuclear Instruments and Methods in Physics Research B 267 (2009) 1662-1665
H. Latreche, G. Bozzolo, P.J. Masset, T. Weber, M. Schütze: Measurements of the coefficient of thermal expansion (CTE) of NiAlMo alloys and comparison with modelling predictions; Materials Science and Engineering: A 527/21-22 (2010) 5837
H.-E. Zschau, P.J. Masset, M. Schütze: Thermodynamical Assessment of the Halogen Effect for Ni-based Superalloys; Proc. 1st International Conference on Materials for Energy, Karlsruhe, 4.-8. July 2010 A281-283
H.-E. Zschau, P.J. Masset, M. Schütze: The Halogen Effect for Ni-Base Superalloys - a Thermodynamic Study; Materials Science Forum 638-642 (2010) 2375-2380
H.-E. Zschau, P.J. Masset, M. Schütze: Screening of the Fluorination Parameters to Improve the Oxidation Resistance of Ni-Base Superalloys at Elevated Temperatures; ECS Transactions 25 (2010) 21-30
H.-E. Zschau, M. Schütze: Application of Accelerators in High Temperature Materials Research; Proc. International Topical Meeting on Nuclear Research Applications and Utilization of Accelerators, Wien/A, 4.-8. May 2009, IAEA, Wien (2010)
K. Aleksandrov, M. Schütze, I. Teliban, E. Quandt: Protective high temperature coatings with sensor function for residual life-time; Proc. EUROCORR 2011 (CD), Stockholm/SE (2011)
K. Aleksandrov, M. Schütze, I. Teliban, C. Thede, E. Quandt: Depletion sensor for protective high temperature coatings; Materials and Corrosion 62 (2011) 706-712
I. Teliban, C. Thede, S. Chemnitz, C. Bechtold, E. Quandt, T. Hüttel, W. Quadakkers, K. Aleksandrov, M. Schütze: Sensor for monitoring the depletion state of high temperature protective coatings; Proc. EUROCORR 2011 (CD), Stockholm/SE (2011)
H.-E. Zschau, M. Schütze: Oxidation Protection of Titanium Aluminides and Ni-base Superalloys at high Temperatures by the Halogen Effect - Principles and Applications; Proc. ISHOC-10, Zushi, Japan (accepted)

Thermal Barrier Coatings

F. Dettenwanger, H. Echsler, C. Bruns, M. Schütze: Investigation of Damage Mechanisms in Thermal Barrier Coatings by Acoustic Emission; in "Elevated Temperature Coatings: Science and Technology III", Eds. J.M. Hampikian, N.B. Dahotre, TMS, Warrendale (1999)
H. Echsler, W. Przybilla, M. Schütze: Investigation of Bondcoat Oxidation and of Mechanical Behaviour of the Bondcoat Oxide for Life Time Prediction of TBC Systems; Proc. Eurocorr 2000 (CD), London
E. Berghof-Hasselbächer, H. Echsler, P. Gawenda, M. Schorr, M. Schütze: Zeit- und temperaturabhängige Entwicklung von physikalischen Defekten in Wärmedämmschichtsystemen; Sonderbände der Praktischen Metallographie 33 (2001) 275-281
R. Herzog, S. Heckmann, R. Steinbrech, D. Sebold, W.J. Quadakkers, F. Schubert, L. Singheiser, H. Echsler, M. Schütze: Contribution to Life Prediction of Thermal Barrier Coatings: A Concept of Accumulated Damage; Proceedings of Materials Week 2001, 1-4 October 2001, Munich
D. Renusch, H. Echsler, M. Schütze: New approaches to the understanding of failure and lifetime prediction of thermal barrier coating systems; in "Lifetime modelling of high temperature corrosion processes", Eds. M. Schütze, W.J. Quadakkers, J.R. Nicholls, Maney Publ., London (2001) 324-336
H. Echsler, D. Renusch, M. Schütze: Kinetics of the evolution of physical defects in the TGO and its vicinity for life time prediction of TBC systems; in "Advanced Thermal Barrier Coatings and Titanium Aluminides for Gas Turbines", DLR, Bonn (2002) 152-156
V. Gauthier, M. Schütze: Oxidation behaviour of γ-TiAl coated with zirconia thermal barriers; in "Advanced Thermal Barrier Coatings and Titanium Aluminides for Gas Turbines", DLR, Bonn (2002) 215-218
V. Gauthier, F. Dettenwanger, M. Schütze: Oxidation behavior of γ-TiAl coated with zirconia thermal barriers; Intermetallics 10 (2002) 667-674
R. Herzog, P. Majerus, E. Trunova, H. Echsler, R.W. Steinbrech, W.J. Quadakkers, F. Schubert, L. Singheiser, H. Echsler, M. Schütze,M.: Plasma-Sprayed Thermal Barrier Coatings for Gas Turbine Components - Degradation Parameters and Modelling Approach; Proceedings of the 2nd International Symposium on Integral Materials Modelling, September 2002, Aachen, Germany
D. Renusch, H. Echsler, M. Schütze: Life time modeling of APS-TBC by using acoustic emission analysis; in "Advanced Thermal Barrier Coatings and Titanium Aluminides for Gas Turbines", DLR, Bonn (2002) 48-52
E. Berghof-Hasselbächer, H. Echsler, P. Gawenda, M. Schorr, M. Schütze: Time and temperature dependent development of physical defects in thermal barrier coating systems; Practical Metallography 40 (2003) 219-231
M. Schütze, D. Renusch, H. Echsler: The influence of oxidation on the life time of thermal barrier coatings; Corrosion 2003, Paper no. 03509, NACE, Houston (2003)
H. Echsler, D. Renusch, M. Schütze: Bond coat oxidation and its significance for life expectancy of thermal barrier coating systems; Materials science and technology 20 (2004) 307-318
H. Echsler, D. Renusch, M. Schütze: Mechanical behaviour of as sprayed and sintered air plasma sprayed partially stabilised zirconia; Materials science and technology 20 (2004) 869-876
D. Renusch, H. Echsler, M. Schütze: Progress in life time modeling of APS-TBC, Part I: residual, thermal and growth stresses including the role of thermal fatigue; Materials at High Temperatures 21 (2004) 65-76
D. Renusch, H. Echsler, M. Schütze: Progress in life time modeling of APS-TBC, Part II: Critical strains, macro-cracking, and thermal fatigue; Materials at High Temperatures 21 (2004) 77-86
D. Renusch, H. Echsler, M. Schütze: The role that interacting failure mechanisms have on the lifetime of APS-TBC under oxidizing conditions; Materials Science Forum 461-464 (2004) 729-736
H.-E. Zschau, M. Dietrich, D. Renusch, M. Schütze, J. Meijer, H.-W. Becker: Detection of Hydrogen in Hidden and Spalled Layers of Turbine Blade Coatings; Nuclear Instruments & Methods in Physics Research B 249 (2006) 381-383
D. Renusch, M. Schütze: Measuring and modeling the TBC damage kinetics by using acoustic emission analysis; Surface & Coatings Technology 202 (2007) 740-744
D. Renusch, M. Schütze: A prototype software tool for life time assessment of thermal barrier coating systems; Materials Science Forum 595-598 (2008) 151-158
D. Renusch, M. Schütze: The role that bond coat depletion of aluminum has on the lifetime of APS-TBC under oxidizing conditions; Materials and Corrosion 59 (2008) 547-555
M. Rudolphi, D. Renusch, M. Schütze: Verification of moisture-induced delayed failure of thermal barrier coatings; Scripta Materialia 59 (2008) 255-257
M. Rudolphi, D. Renusch, H.-E. Zschau, M. Schütze: Hydrogen detection in buried layers of thermal barrier coatings; Materials Science Forum 595-598 (2008) 177-184
M. Rudolphi, D. Renusch, H.-E. Zschau, M. Schütze, J. Meijer: The effect of moisture on the delayed spallation of thermal barrier coatings; Materials at High Temperatures 26 (2009) 325-329
H. Aleksanoglu, M. Rudolphi, D. Renusch, T.S. Mao, A. Scholz, C. Berger, M. Schütze: Untersuchung der Rissausbreitung in Wärmedämmschichtsystemen unter thermomechanischer Beanspruchung; Tagungsband FVV Informationstagung Turbomaschinen, Heft R552 (2010) 131-158
D. Renusch, M. Rudolphi, M. Schütze: Software tools for lifetime assessment of thermal barrier coatings, Part I - Thermal ageing failure and thermal fatigue failure; Journal of Solid Mechanics and Materials Engineering 4 (2010) 143-154
D. Renusch, M. Rudolphi, M. Schütze: Software tools for lifetime assessment of thermal barrier coatings, Part II - Bond coat aluminum depletion failure; Journal of Solid Mechanics and Materials Engineering 4 (2010) 155-166
M. Schütze, M. Rudolphi: Prediction of Mechanical Scale Failure - Current Status and Perspectives; Materials Science Forum 696 (2011) 138-143

Coatings for Thermal Power Stations

G. Strehl, V. Guttmann, D. Naumenko, A. Kolb-Telieps, G. Borchardt, W.J. Quadakkers, J. Klöwer, P.A. Beaven, J.R. Nicholls: The influence of sample geometry on the oxidation and chemical failure of FeCrAl(RE) alloys; in "Lifetime modelling of high temperature corrosion processes", Eds. M. Schütze, W.J. Quadakkers, J.R. Nicholls, Maney Publ., London (2001) 107-122
V. Rohr, A. Donchev, M. Schütze: Diffusion coatings for the high temperature corrosion protection of 9-12% Cr steels; Proc. EUROCORR 2004 Nice/F (CD) (2004), paper no. 237
V. Rohr, M. Schütze: Diffusion coatings for heat exchanger materials; Surface Engineering 20 (2004) 266-274
V. Rohr, M. Schütze: Novel low temperature diffusion coatings for heat exchanger materials; Materials Science Forum 461-464 (2004) 401-408
E. Huttunen-Saarivirta, S. Kalidakis, F.H. Stott, V. Rohr, M. Schütze: The erosion-corrosion resistance of uncoated and aluminized 12% chromium ferritic steels under fluidized-bed conditions at elevated temperature; Materials and Corrosion 56 (2005) 897-906
J. Kalivodova, D. Baxter, M. Schütze, V. Rohr: Gaseous corrosion of alloys and novel coatings in simulated environments for coal, waste and biomass boilers; Materials and Corrosion 56 (2005) 882-889
A. Littner, F. Pedraza, A.D. Kennedy, P. Moretto, L. Peichl, T. Weber, M. Schütze: Performance and thermal stability of Pt-modified Al-diffusion coatings for superalloys under cyclic and isothermal conditions; Proceedings of the sixth international conference on the Microscopy of Oxidation, Birmingham, 4.-6. April 2005, Eds. G.J. Tatlock, H.E. Evans (2005) 245-254
L. Nieto Hierro, V. Rohr, P.J. Ennis, M. Schütze, W.J. Quadakkers: Steam oxidation and its potential effects on creep strength of power station materials; Materials and Corrosion 56 (2005) 890-896
V. Rohr, A. Donchev, M. Schütze, A. Milewska, F.J. Pérez: Diffusion coatings for high temperature corrosion protection of 9-12%Cr steels; Corrosion Engineering, Science and Technology 40 (2005) 226-232
V. Rohr, M. Schütze, E. Fortuna, D.N. Tsipas, A. Milewska, F.J. Perez: Development of novel diffusion coatings for 9-12% Cr ferritic-martensitic steels; Materials and Corrosion 56 (2005) 874-881
V. Rohr, M. Schütze, P. Maugis, D. Poquillon, D. Monceau: Mechanism of the pack cementation process at low temperature on 9% Cr steels; Proc. Eurocorr 2005, Lissabon 2005 (CD)
T. Weber, M. Schütze: Diffusion coatings for corrosion protection of high temperature structural materials; Defect and Diffusion Forum 237-240 (2005) 922-927
E. Berghof-Hasselbächer, V. Rohr, E. Nicolas, M. Schütze: The determination of Al-diffusion layer thickness by image processing; Practical Metallography 43 (2006) 127-142
E. Huttunen-Saarivirta, V. Rohr, F.H. Stott, M. Schütze: Influence of glass bead blasting of 9%Cr steel substrate on development of aluminide diffusion coatings; Surface Engineering 22 (2006) 472-480
E. Huttunen-Saarivirta, F.H. Stott, V. Rohr, M. Schütze: Particle angularity effects on the elevated-temperature erosion-oxidation behaviour of aluminium diffusion; Wear 261 (2006) 746-759
L. Niewolak, M. Malessa, S. Y. Coleman, W. J. Quadakkers, M. Schütze: Influence of cycling parameter variation on thermal cyclic oxidation testing of high temperature materials (COTEST); Materials and Corrosion 57 (2006) 31-42
E. Huttunen-Saarivirta, F.H. Stott, V. Rohr, M. Schütze: Erosion-oxidation behavior of chromized-aluminized 9% chromium steel under fluidized-bed conditions at elevated temperature; Oxidation of Metals 68 (2007) 113-132
E. Huttunen-Saarivirta, F.H. Stott, V. Rohr, M. Schütze: Erosion-oxidation behaviour of pack-aluminized 9% chromium steel under fluidized-bed conditions at elevated temperature; Corrosion Science 49 (2007) 2844-2865
E. Huttunen-Saarivirta, S. Kalidakis, F.H. Stott, V. Rohr, M. Schütze: Erosion-Oxidation of Uncoated, Aluminized and Chromized-Aluminized 9Cr-1Mo Steels Under Fluidized-Bed Conditions at 550°C to 700°C; Tribology International 43 (2010) 161-170
X. Montero, M. Galetz, M. Schütze: A single step process to form in-situ an alumina foam/aluminide TBC system for alloys in extreme environments at high temperatures; Surface and Coatings Technology, In Press, Corrected Proof, Available online 20 June 2011

Materials and Coatings for Sulfidizing Environments

B. Glaser, M. Schütze, F. Vollhardt: Auswertung von Daten zum H₂S-Angriff auf Stähle bei verschiedenen Temperaturen und Konzentrationen; Chem. Ing. Techn. 63 (1991) 634
M. Schulte, M. Schütze: Sulfide Scales for the Protection of Steels in H₂S-Containing Atmospheres; in "Corrosion Control for Low-Cost Reliability", NACE, Houston 1993
M. Schulte, M. Schütze: The Behaviour of Protective Sulfide Scales on Various Steels in H₂S-Containing Atmospheres during Temperature Changes; in "Progress in the Understanding and Prevention of Corrosion", Eds. J.M. Costa, A.D. Mercer, The Institute of Materials, London (1993) 750
M. Schütze: Einfluß von Temperaturänderungen auf das Verhalten schützender Sulfidschichten; Materials and Corrosion 47 (1996) 103-105
M. Schütze, M. Nöth: The Sulfidation Resistance of Several Fe- and Ni-Base Alloys and of Two Intermetallics in Atmospheres Containing H₂S at 400-700ºC; Proc. 13th ICC, Australasian Corrosion Association, Melbourne (1996) 1534-1542
K. Rahts, M. Nöth, M. Schulte, M. Schorr, P. Gawenda, M. Schütze: Untersuchungen an Sulfidschichten verschiedener Hochtemperaturwerkstoffe aus thermischer Beanspruchung in H₂S-haltiger Atmosphäre; Sonderbände der Praktischen Metallographie 28 (1997) 229-236
M. Schütze, M. Nöth: Materials for High Temperature Sulfidation Resistant Coatings; Proc. EUROCORR '97, NKF, Oslo (1997) 79-84
M. Schütze, M. Nöth: Protective Coatings for High Temperatures and High Sulfur-Low Oxygen Environments; in "Corrosion 98", NACE Houston (1998) 188/1-14
M. Schulte, A. Rahmel, M. Schütze: The Sulfidation Behavior of Several Commercial Ferritic and Austenitic Steels; Oxidation of Metals 49 (1998) 33-70
J. Jimenez Soler, J.F. Norton, M. Nöth, M. Schütze: The Corrosion Behaviour of a TiAl Coating Exposed to a Simulated Dry-feed Entrained Slagging Coal Gasifier Atmosphere Containing 0.8 % H₂S at 600°C; Materials and Corrosion 50 (1999) 373-446
M. Schulte, M. Schütze: The Role of Scale Stresses in the Sulfidation of Steels; Oxidation of Metals 51 (1999) 55-77
T. Weber, M. Schütze: Development of Protective Coatings for Reducing Environments at High Temperatures; in CORROSION 99, Paper No. 72, NACE, Houston (1999)
T. Weber, M. Schütze: Protective Coatings for Reducing and Sulfidizing Environments; in "Solution of Corrosion Problems in Advanced Technologies", Eds. G. Schmitt, M. Schütze, Chapter 2/6, DECHEMA, Frankfurt am Main (1999)
T. Weber, M. Schütze: Protective Coatings for Reducing Sulfidizing Environments at High Temperatures; Proc. China International Corrosion Control Conference '99 (CICCC'99), Eds. Z. Ren et al., China Chemical Anticorrosion Technology Association, Beijing (1999) 359-363
B. Aumüller, T. Weber, M. Schütze: Verfahrenstechnische Aspekte und Schutzwirkung von thermisch gespritzten TiAl-Schutzschichten für reduzierende Atmosphären; in "Schutzschichten für Hochtemperaturanwendungen", FDS, Dresden (2000)
T. Weber, M. Schütze: Coatings against high temperature H₂S-Corrosion; Proc. EUROCORR 2001 (CD) Associazione Italiana di Metallurgia, Milano (2001)
B. Aumüller, T. Weber, M. Schütze: Thermal spray coatings for reducing sulfidizing atmospheres at high temperatures; Proc. Int. Thermal Spray Conference 2002, Ed. E. Lugscheider, DVS-Verlag, Düsseldorf (2002)
M. Schütze: High temperature corrosion - A materials challenge in modern high temperature technology; Ochrona przed korozja 45 (2002) 87-96
T. Weber, C. Rosado, M. Schütze: Development of Coatings for Environments with high sulfur and/or carbon activities at low oxygen potentials; CORROSION 2002, NACE, Houston (2002) 02371/1-12
M. Schütze, M. Spiegel: Korrosion in Anlagen zur thermischen Abfallverwertung; Proc. Jahrestagung 2004 der GfKORR - Gesellschaft für Korrosionsschutz e.V., Korrosionsschutz in der Chemieindustrie (CD), GfKORR, Frankfurt am Main (2004)
T. Weber, M. Schütze: Kodiffusionsschichten aus Aluminium, Silizium und Titan zur Verbesserung der Hochtemperatur-Korrosionsbeständigkeit von Apparatebauwerkstoffen; in "Neue Materialien und Verfahren in der Beschichtungstechnik", Tagungsband zum 7. Werkstofftechnischen Kolloquium, Hrsg. B. Wielage, Chemnitz (2004) 181-186
M. Schütze, M. Malessa, V. Rohr, T. Weber: Development of Coatings for Protection in Specific High Temperature Environments; Surface & Coatings Technology 201 (2006) 3872-3879
M. Schütze, H.K. Steinberg: Ursachen und Mechanismen der Korrosion in thermischen Anlagen; Verfahren & Werkstoffe für die Energietechnik: Korrosion in Anlagen zur regenerativen Energieerzeugung, Eds. M. Faulstich, D. Bendix, Förster Verl., Sulzbach-Rosenberg 2 (2006) 25-50
M. Schütze: Corrosion Resistance at elevated temperatures in highly aggressive environments; CORROSION 63 (2007) 4-18
B. Rammer, T. Weber, M. Schütze: Diffusion coatings for aggressive high-temperature process environments; Proc. EUROCORR 2008 (CD), Edinburgh/UK (2008)

Materials and Coatings for Carburizing and Metal Dusting Environments

U.J. Brand, H.-E. Bühler, P. Karduck, S. Köhler, E. Berghof-Hasselbächer, M. Schütze: Damage Caused by Oxidation and Carburisation at a Valve of a Dehydrating Unit; Practical Metallography 36 (1999) 405-422
U.J. Brand, H.-E. Bühler, P. Karduk, S. Köhler, E. Berghof-Hasselbächer, M. Schütze: Investigations of a Valve Damaged by Oxidation and Carburisation; in "Solution of Corrosion Problems in Advanced Technologies", Eds. G. Schmitt, M. Schütze, Chapter 2/27, DECHEMA, Frankfurt am Main (1999)
F. Dettenwanger, D. Grotmann, H. Friedrich, E. Berghof-Hasselbächer, M. Schorr, M. Schütze: Damage of a Heat-treatment Retort by Metal Dusting Attack; Materials and Corrosion 50 (1999) 289-293
C. Rosado, F. Dettenwanger, M. Schütze: Development of coatings against metal dusting attack; Proc. Int. Workshop Metal Dusting, 2000, Argonne National Lab., Argonne (2001) 213-224
C. Rosado, F. Dettenwanger, M. Schütze: Protection of steels against metal dusting attack by coatings; Proc. EUROCORR 2001 (CD) Associazione Italiana di Metallurgia, Milano (2001)
M. Schütze, C. Rosado, F. Dettenwanger: Protection of steels against metal dusting attack by coatings; Proc. Stainless Steel World 2001, KCI Publishing, Zutphen/NL (2001) 306-314
E. Berghof-Hasselbächer, H.-E. Bühler, O. Greven, M. Schorr, J. Schürhoff, M. Schütze: Investigations on Component Failure of Grate Systems During Residual Wood Combustion; Practical Metallography 39 (2002) 369-386
E. Berghof-Hasselbächer, C. Rosado Sainz-Rosas, M. Schütze: Korrosionsschutzschichten gegen Metal Dusting Angriff; Sonderbände der Praktischen Metallographie 34, Ed. G. Petzow, Werkstoff-Informationsgesellschaft, Frankfurt am Main (2002) 271-281
M. Schütze: High temperature corrosion - A materials challenge in modern high temperature technology; Ochrona przed korozja 45 (2002) 87-96
T. Weber, C. Rosado, M. Schütze: Development of Coatings for Environments with high sulfur and/or carbon activities at low oxygen potentials; CORROSION 2002, NACE, Houston (2002) 02371/1-12
E. Berghof-Hasselbächer, C. Rosado Sainz-Rozas, M. Schütze: Protective Coatings to Prevent Metal Dusting; Practical Metallography 40 (2003) 407-419
M. Schütze: Metal Dusting, Carburization and Nitridation; Materials and Corrosion 54 (2003) 735; Protective behaviour of newly developed coatings against metal dusting; Materials and Corrosion 54 (2003) 831-854
T. Weber, M. Schütze: Kodiffusionsschichten aus Aluminium, Silizium und Titan zur Verbesserung der Hochtemperatur-Korrosionsbeständigkeit von Apparatebauwerkstoffen; in "Neue Materialien und Verfahren in der Beschichtungstechnik", Tagungsband zum 7. Werkstofftechnischen Kolloquium, Hrsg. B. Wielage, Chemnitz (2004) 181-186
M. Schütze, M. Malessa, V. Rohr, T. Weber: Development of Coatings for Protection in Specific High Temperature Environments; Surface & Coatings Technology 201 (2006) 3872-3879
M. Schütze, H.K. Steinberg: Ursachen und Mechanismen der Korrosion in thermischen Anlagen; Verfahren & Werkstoffe für die Energietechnik: Korrosion in Anlagen zur regenerativen Energieerzeugung, Eds. M. Faulstich, D. Bendix, Förster Verl., Sulzbach-Rosenberg 2 (2006) 25-50
D. Röhnert, F. Phillipp, H. Reuther, T. Weber, E. Wessel, M. Schütze: Initial Stages in the Metal-dusting Process on Alloy 800; Oxidation of Metals 68 (2007) 271-293
D. Röhnert, M. Schütze, T. Weber: Performance of several nickel base alloys in metal dusting atmospheres; NACE Corrosion 2007, Paper 074175/1-16
C. Rosado, M. Schütze: Protective behaviour of newly developed coatings against metal dusting; in "Corrosion by carbon and nitrogen: Metal dusting, carburisation and nitridation", Hrsg. H.J. Grabke, M. Schütze, Woodhead Publishing, Cambridge (2007) 103-153
M. Schütze: Corrosion Resistance at elevated temperatures in highly aggressive environments; CORROSION 63 (2007) 4-18
C. Geers, T. Weber, M. Schütze: New approach for the inhibition of carbon deposition on steel surfaces under metal dusting conditions; Proc. EUROCORR 2008 (CD), Edinburgh/UK (2008)
B. Rammer, T. Weber, M. Schütze: Diffusion coatings for aggressive high-temperature process environments; Proc. EUROCORR 2008 (CD), Edinburgh/UK (2008)
C. Geers, M. Schütze: New surface protection system against Metal Dusting; Proc. NACE 2009 (CD), Atlanta/GA/USA (2009)
C. Geers, M. Schütze: Non-oxidizing intermetallic phases as an alternative to oxide forming coatings against coking and metal dusting; Proc. Aachener-Ölwärme-Kolloquium 2009, Shaker-Verlag, Aachen (2009) 204
C. Geers, M. Schütze: Selective inhibition of metals on material surfaces catalyzing the metal dusting process; ECS Transactions 25 (2009) 71-76
C. Geers, M. Schütze: Behavior of nickel-tin coated high temperature materials exposed under metal dusting conditions; Proc. NACE 2011 (CD), Houston/TX/USA (2011)
C. Geers, M. Schütze: Lifetime Extension of Alloys for Metal Dusting Applications; Proc. EUROCORR 2011 (CD), Stockholm/SE (2011)
D.J. Young, J. Zhang, C. Geers, M. Schütze: Recent advances in understanding metal dusting: A review; Materials and Corrosion 62 (2011) 7-28

Materials and Coatings for Halogen-containing Environments

M. Schütze, P. Simon: Materials for Use in Atmospheres Containing HF in a Pyrohydrolysis Plant for Re-Processing Spent Pot Lining from Aluminium Production; Materials and Corrosion 45 (1994) 435-443
M. Schütze, B. Glaser: The Influence of Cl-Containing Atmospheres on Creep Crack Growth at 800ºC; in "Heat-Resistant Materials II", Eds. K. Natesan et al., ASM International, Materials Park (Ohio) (1995) 343-351
A. Jeutter, M. Schütze: The Influence of HCl-containing Atmospheres on High Temperature Corrosion of Coated and Uncoated Nickel-Base Superalloys under Complex Loading Conditions; Proc. EUROMAT 97, Bd. 1, Netherlands Society for Materials Science, Zwijndrecht/NL (1997) 223-226
K. Rahts, M. Schorr, C. Schwalm, M. Schütze: Untersuchungen über den Einfluß von Chlor bei der Hochtemperaturoxidation; Practical Metallography 29 (1998) 305-311
M. Schütze, A. Jeutter: High temperature corrosion resistance of gas turbine materials and coatings under the influence of Cl-contaminations; in "Materials for advanced power engineering 1998", Eds. J. Lecomte-Beckers et al., Series Energietechnik, Vol. 5, Forschungszentrum Jülich (1998) 1543-1552
R. Bender, M. Schütze: Corrosion Behaviour of Several Commercial Alloys in Oxidizing-Chloridizing Gas Mixtures at 650 to 1000°C; in "Solution of Corrosion Problems in Advanced Technologies", Eds. G. Schmitt, M. Schütze, Chapter 2/14, DECHEMA, Frankfurt am Main (1999)
A. Jeutter, M. Schütze: The Role of HCl Impurities in the Environment and Y for the High Temperature Corrosion of CoNiCrAl(Y)-Coatings on a Ni-base Superalloy under Complex Loading Conditions; Materials at High Temperatures 16 (1999) 71-86
K. Rahts, M. Schorr, C. Schwalm, M. Schütze: Water-free Methods of Preparation for the Analysis of Chlorides in the High Temperature Oxidation in Chlorine Containing Atmospheres; Practical Metallography 36 (1999) 86-97
R. Bender, M. Schütze: Oxidation Behavior of Several Commercial Alloys in Chlorine-Containing High Temperature Environments; CORROSION 2000, Paper No. 239, NACE, Houston (2000)
C. Schwalm, M. Schütze: The Corrosion Behavior of Several Heat Resistant Materials in Air + 2 Vol-% Cl₂ at 300 to 800°C Part I - Fe-Base and Fe-Containing Alloys; Materials and Corrosion 51 (2000) 34-49
C. Schwalm, M. Schütze: The Corrosion Behavior of Several Heat Resistant Materials in Air + 2 Vol-% Cl₂ at 300 to 800°C Part 2 - Nickel Base Alloys; Materials and Corrosion 51 (2000) 73-79
C. Schwalm, M. Schütze: The Corrosion Behavior of Several Heat Resistant Materials in Air + 2 Vol-% Cl₂ at 300 to 800°C Part 3 - Alumina Formers and Intermetallics; Materials and Corrosion 51 (2000) 161-172
R. Bender, M. Schütze: Corrosion behaviour of several commercial alloys in oxidizing-chloridizing environments at 650-1000°C; Proc. EUROCORR 2001 (CD), Associazione Italiana di Metallurgia, Milano (2001)
M. Schütze, R. Bender: Hochtemperaturkorrosion in chlorhaltigen Atmosphären - Leistungsfähigkeit metallischer Werkstoffe und Möglichkeiten zur Erhöhung der Beständigkeit; in "Hochlegierte Werkstoffe - Korrosionsverhalten und ihre Anwendung", Vol. 3, TAW-Verlag, Wuppertal (2001)
M. Schütze: High temperature corrosion - A materials challenge in modern high temperature technology; Ochrona przed korozja 45 (2002) 87-96
R. Bender, M. Schütze: The role of alloying elements in commercial alloys for corrosion resistance in oxidizing-choridizing atmospheres Part I: Literature evaluation and thermodynamic calculations on phase stabilities; Materials and Corrosion 54 (2003) 567-586
R. Bender, M. Schütze: The role of alloying elements in commercial alloys for corrosion resistance in oxidizing-chloridizing atmospheres - Part 2: Experimental investigations; Materials and Corrosion 54 (2003) 652-686
M. Schütze, M. Spiegel: Korrosion in Anlagen zur thermischen Abfallverwertung; Proc. Jahrestagung 2004 der GfKORR - Gesellschaft für Korrosionsschutz e.V., Korrosionsschutz in der Chemieindustrie (CD), GfKORR, Frankfurt am Main (2004)
T. Weber, R. Bender, M. Schütze: Hochtemperaturkorrosion in chlorhaltiger Verbrennungsatmosphäre - Schutzkonzepte für metallische Werkstoffe; Optimierung der Abfallverbrennung 1, K.J. Thomé-Kozmiensky (Ed.), TK-Verlag, Neuruppin (2004) 581-598
M. Schütze, M. Malessa, V. Rohr, T. Weber: Development of Coatings for Protection in Specific High Temperature Environments; Surface & Coatings Technology 201 (2006) 3872-3879
M. Schütze, H.K. Steinberg: Ursachen und Mechanismen der Korrosion in thermischen Anlagen; Verfahren & Werkstoffe für die Energietechnik: Korrosion in Anlagen zur regenerativen Energieerzeugung, Eds. M. Faulstich, D. Bendix, Förster Verl., Sulzbach-Rosenberg 2 (2006) 25-50
H. Latreche, G. Tegeder, G. Wolf, P.J. Masset, T. Weber, M. Schütze: High temperature corrosion behaviour of NiAlMo APS-coatings in chlorine-based atmospheres; Proc. EUROCORR 2007 (CD), Freiburg (2007)
M. Schütze: Corrosion Resistance at elevated temperatures in highly aggressive environments; CORROSION 63 (2007) 4-18
H. Latreche, S. Doublet, G. Wolf, G. Tageder, P.J. Masset, T. Weber, M. Schütze: Behaviour of NiAl APS-coatings in chlorine-containing atmospheres; Materials and Corrosion 59 (2008) 573-583; Proc. NACE Corrosion 2008, New Orleans/USA (2008)
H. Latreche, G. Tegeder, G. Wolf, P.J. Masset, T. Weber, M. Schütze: New approaches to improve high temperature corrosion resistance in chlorine-based atmospheres; Materials Science Forum 595-598 (2008) 307-321
B. Rammer, T. Weber, R. Bender, M. Schütze: Material solutions for the thermal treatment in high chlorine environments; Proc. NACE Corrosion 2008, New Orleans/USA (2008)
B. Rammer, T. Weber, M. Schütze: Diffusion coatings for aggressive high-temperature process environments; Proc. EUROCORR 2008 (CD), Edinburgh/UK (2008)
B. Rammer, T. Weber, M. Schütze: Entwicklung von Diffusionsschichten auf Nickelbasiswerkstoffen für den Einsatz in chlorhaltigen Hochtemperaturprozessen; Mat.-wiss. u. Werkstofftech. 39 (2008) 29-32
E. Berghof-Hasselbächer, P.J. Masset, D. Texier, G. Schmidt, P. Gawenda, M. Jusek, M. Schütze: Mikrostrukturen von NiAl_(1-x)Hf_(x)-Legierungen (x=0…0,2); Sonderbände der Praktischen Metallographie 41 (2009) 113-119
H. Latreche, S. Doublet, M. Schütze: Development of Corrosion Assessment Diagrams for High Temperature Chlorine Corrosion. Part I: State of the Art and Development of the Basis for a New Extended Approach; Oxidation of Metals 72 (2009) 1-30
H. Latreche, S. Doublet, M. Schütze: Development of Corrosion Assessment Diagrams for High Temperature Chlorine Corrosion. Part II: Development of "Dynamic" Quasi-stability Diagrams; Oxidation of Metals 72 (2009) 31-65
P.J. Masset, D. Texier, M. Schütze: Coefficients of thermal expansion of (Ni_0.5Al_0.5)_1-xHf_x alloys (x = 0 ... 0.2); Materials Science and Technology 25 (2009) 874-879
B. Rammer, T. Weber, M. Schütze: Diffusion coatings for aggressive high temperature process environments; Corrosion Engineering, Science and Technology 44 (2009) 227-233
B. Rammer, T. Weber, M. Schütze: Diffusion coatings for oxidizing high-chlorine environments at elevated temperatures; Proc. ICMCTF 2009, San Diego/USA (2009)
B. Rammer, M. Schütze: A New Coating Concept for Oxidizing High Chlorine Environments; Proc. NACE Corrosion 2011, Houston/USA (2011)

Titanium Aluminides

S. Becker, A. Rahmel, M. Schorr, M. Schütze: Mechanism of Isothermal Oxidation of the Intermetallic TiAl and of TiAl Alloys; Oxidation of Metals 38 (1992) 425-464
S. Becker, M. Schütze, A. Rahmel: Cyclic-Oxidation Behavior of TiAl and of TiAl Alloys; Oxidation of Metals 39 (1993) 93-106
M. Schütze, M. Schmitz: The Oxidation Behaviour of Titanium Aluminide under the Effect of Mechanical Stresses; Trans. Mat. Res. Soc. Jpn. 14A (1994) 219-224
A. Rahmel, W.J. Quadakkers, M. Schütze: Fundamentals of TiAl Oxidation - A Critical Review; Materials and Corrosion 46 (1995) 271-285
K. Rahts, M. Schorr, M. Schütze, M. Schmitz-Niederau: Darstellung von Oxidschichten und Gefüge von TiAl-Legierungen aus Hochtemperaturversuchen; Practical Metallography 27 (1995) 561-565
M. Schütze, M. Schmitz-Niederau: Interaction of Mechanical Loading and Oxidation at 900ºC for TiAl; in "Gamma Titanium Aluminides", Eds. Y.-W. Kim, R. Wagner, M. Yamaguchi, TMS Warrendale (1995) 83-92
C. Lang, M. Schütze: TEM Investigations of the Early Stages of TiAl Oxidation; Oxidation of Metals 46 (1996) 255-285
M. Schütze: Intermetallic Titanium Aluminides - Importance of Oxidation Resistance for Applications; Proc. Conf. Corrosion '96 - Theory and Practice, Ed. R. Juchniewicz, Politechnika Gdanska, Gdansk (1996) 41-58
M. Hald, M. Schütze: Isothermal Oxidation of P/M-TiAl Alloys; Materials Science Forum 251-254 (1997) 179-186
C. Lang, M. Schütze: Die Mechanismen der Anfangsoxidation und ihre Auswirkungen auf die Oxidationsbeständigkeit von Titanaluminiden; Proc. Werkstoffwoche 96, Eds. F. Aldinger, H. Mughrabi (1997) 871-876
C. Lang, M. Schütze: The Initial Stages in the Oxidation of TiAl; Materials and Corrosion 48 (1997) 13-22
M. Schütze, M. Hald: Improvement of the Oxidation Resistance of TiAl Alloys by Using the Chlorine Effect; Materials Science and Engineering A 239-240 (1997) 847-858
M. Schütze, M. Hald, C. Lang. S. Melsheimer, A. Rahmel: Intermetallic disilicides and titanium aluminides - a new class of structural high temperature materials under the aspect of their high temperature oxidation resistance; Pure & Appl. Chem. 69 (1997) 2335-2341
G. Schumacher, F. Dettenwanger, M. Hald, C. Lang, M. Schütze: The microalloying effect in the oxidation of TiAl-alloys; in "Solutions to corrosion problems", Jaarbeurs, Utrecht (1998)
F. Dettenwanger, M. Schütze: Isothermal Oxidation of α₂-Ti₃Al between 800 and 1000°C; in "Solution of Corrosion Problems in Advanced Technologies", Eds. G. Schmitt, M. Schütze, Chapter 2/28, DECHEMA, Frankfurt am Main (1999)
U. Hornauer, E. Richter, E. Wieser, W. Möller, G. Schumacher, C. Lang, M. Schütze: Improvement of the High Temperature Oxidation Resistance of Ti50 Al via Ion-Implantation; Nuclear Instruments and Methods in Physics Research B148 (1999) 858-862
M. Schmitz-Niederau, M. Schütze: The Oxidation Behaviour of Several Ti-Al Alloys at 900°C in Air; Oxidation of Metals 52 (1999) 225-240
M. Schmitz-Niederau, M. Schütze: Cracking and Healing of Oxide Scales on Ti-Al Alloys at 900°C; Oxidation of Metals 52 (1999) 241-276
G. Schumacher, F. Dettenwanger, M. Schütze, U. Hornauer, E. Richter, E. Wieser, W. Möller: Microalloying Effects in the Oxidation of TiAl Materials; Intermetallics 7 (1999) 1113-1120
G. Schumacher, C. Lang, M. Schütze, U. Hornauer, E. Richter, E. Wieser, W. Möller: Improvement of the Oxidation Resistance of γ-Titanium Aluminides by Microalloying with Chlorine using Ion Implantation; Materials and Corrosion 50 (1999) 162-165
A. Zeller, F. Dettenwanger, M. Schütze: Influence of Water Vapor on the Creep Behaviour of TiAl; in "Gamma Titanium Aluminides 1999", Eds. Y.-W. Kim et al., TMS, Warrendale (1999) 761-768
A. Zeller, F. Dettenwanger, M. Schütze: Influence of Water Vapour on the Oxidation Behaviour of TiAl at 700 and 750°C; in "Solution of Corrosion Problems in Advanced Technologies", Eds. G. Schmitt, M. Schütze, Chapter 2/31, DECHEMA, Frankfurt am Main (1999)
F. Dettenwanger, M. Schütze: Isothermal Oxidation of α₂-Ti₃Al; Oxidation of Metals 54 (2000) 121-138
U. Hornauer, R. Günzel, H. Reuther, E. Richter, E. Wieser, W. Möller, G. Schumacher, F. Dettenwanger, M. Schütze: Protection of γ-based TiAl Against High Temperature Oxidation Using Ion Implantation of Chlorine; Surface and Coatings Technology 125 (2000) 89-93
U. Hornauer, E. Richter, W. Matz, H. Reuther, A. Mücklich, E. Wieser, W. Möller, G. Schumacher, M. Schütze: Microstructure and oxidation kinetics of intermetallic TiAl after Si- and Mo- ion implantation; Surface and Coatings Technology 128-129 (2000) 418-422
A. Ralison, F. Dettenwanger, M. Schütze: Oxidation of Orthorhombic Ti2AlNb Alloys at 800°C in Air; Materials and Corrosion 51 (2000) 317-328
A. Ralison, F. Dettenwanger, M. Schütze: Oxidation in air and hot corrosion behavior of orthorhombic Ti2AlNb alloys; Proc. Eurocorr 2000 (CD), London
M. Schütze, G. Schumacher, F. Dettenwanger, U. Hornauer, E. Richter, E. Wieser, W. Möller: Einfluß einer oberflächennahen Dotierung auf die Oxidationskinetik von TiAl-Werkstoffen; in "Schutzschichten für Hochtemperaturanwendungen", FDS, Dresden (2000)
G. Schumacher, F. Dettenwanger, M. Schütze: Investigations of the Microalloying Effect of Chlorine in the Oxidation of TiAl Alloys; Materials at High Temperatures 17 (2000) 53-58
G. Schumacher, F. Dettwanger, M. Schütze, A. Iberl, D. Reil: XRD Investigations of the Phosphorus Effect on the Oxidation of TiAl Alloys by High-Resolution Methods; Oxidation of Metals 54 (2000) 317-337
C. Bruns, M. Schütze: Investigation of the Mechanical Properties of Oxide Scales on Nickel and TiAl; Oxidation of Metals 55 (2001) 35-68
A. Donchev, M. Schütze: Improvement of the oxidation resistance of γ-TiAl alloys by ion implantation; in "Advanced Thermal Barrier Coatings and Titanium Aluminides for Gas Turbines", DLR, Bonn (2002) 134-136
V. Gauthier, F. Dettenwanger, M. Schütze: Oxidation behavior of γ-TiAl coated with zirconia thermal barriers; Intermetallics 10 (2002) 667-674
V. Gauthier, M. Schütze: Oxidation behaviour of γ-TiAl coated with zirconia thermal barriers; in "Advanced Thermal Barrier Coatings and Titanium Aluminides for Gas Turbines", DLR, Bonn (2002) 215-218
W. Przybilla, M. Schütze: Growth stresses in the oxide scales on TiAl alloys at 800 and 900°C; Oxidation of Metals 58 (2002) 337-359
M. Schütze, A. Donchev, V. Gauthier, H.-E. Zschau: Improvement of the oxidation resistance of intermetallic TiAl alloys by the halogen effect; Proc. 15 Int. Corr. Congress, Granada (CD) (2002) Paper 782
M. Schütze, G. Schumacher, F. Dettenwanger, U. Hornauer, E. Richter, E. Wieser, W. Möller: The halogen effect in the oxidation of intermetallic titanium aluminides; Corrosion Science 44 (2002) 303-318
A. Zeller, F. Dettenwanger, M. Schütze: Influence of water vapour on the creep and fatigue properties of TiAl; Intermetallics 10 (2002) 33-57
A. Zeller, F. Dettenwanger, M. Schütze: Influence of water vapour on the oxidation behaviour of titanium aluminides; Intermetallics 10 (2002) 59-72
H.-E. Zschau, V. Gauthier, M. Schütze, H. Baumann, K. Bethge: Investigation of the fluorine microalloying effect in the oxidation of TiAl at 900°C in air; in "Advanced Thermal Barrier Coatings and Titanium Aluminides for Gas Turbines", DLR, Bonn (2002) 210-214
A. Donchev, B. Gleeson, M. Schütze: Thermodynamic considerations of the beneficial effect of halogens on the oxidation resistance of TiAl-based alloys; Intermetallics 11 (2003) 387-398
A. Donchev, M. Schütze, E. Richter, U. Hornauer, E. Wieser: Erhöhung der Oxidationsbeständigkeit von TiAl-Legierungen durch Ionenimplantation; Tagungsband 1, KKF-Kolloquium "Problemlösungen für den metallischen Leichtbau", January 2003, GfKORR e.V., Frankfurt (2003)
V. Gauthier, F. Dettenwanger, M. Schütze, V. Shemet, W.J. Quadakkers: Oxidation-resistant aluminide coatings on γ-TiAl; Oxidation of Metals 59 (2003) 233-255
U. Hornauer, E. Richter, E. Wieser, W. Möller, A. Donchev, M. Schütze: Plasma immersion ion implantation of TiAl using chlorine containing plasma; Surface and Coatings Technology 173-174 (2003) 1182-1186
A. Ralison, F. Dettenwanger, M. Schütze: Oxidation of orthorhombic Ti2AlNb alloys in the temperature range 550-1000°C in air; Proceedings of the Fifth International Conference on the Microscopy of Oxidation, Limerick, 26-28 August 2002, Eds. S.B. Newcomb, G. Tatlock (2003) 361-383
A. Ralison, F. Dettenwanger, M. Schütze: Oxidation of orthorhombic Ti2AlNb alloys in the temperature range 550-1000°C in air; Materials at High Temperatures 20 (2003) 607-629
H.-E. Zschau, V. Gauthier, G. Schumacher, F. Dettenwanger, M. Schütze, H. Bauman: Investigation of the fluorine microalloying effect in the oxidation of TiAl at 900°C in Air; Oxidation of Metals 59 (2003) 183-200
H.-E. Zschau, M. Schütze, H. Baumann, K. Bethge: Formation of an Alumina Scale after Fluorine Application and Oxidation of TiAl at 900°C in Air; Proceedings of the 203rd Meeting of The Electrochemical Society, Pennington (2003)
H.-E. Zschau, M. Schütze, H. Baumann, K. Bethge: Investigation of the fluorine microalloying effect in the oxidation of TiAl at 900°C in Air; Proceedings of the 203rd Meeting of The Electrochemical Society, Pennington (2003)
H.-E. Zschau, M. Schütze, H. Baumann, K. Bethge: Investigation of the mechanism of the fluorine microalloying effect at the oxidation of TiAl using nuclear physics methods; Proceedings of the Michal Smialowski International Symposium on Corrosion and Hydrogen Degradation: Advances in Corrosion Science and Application. 9.-13.9.2003, Zakopane (2003) 187-192
A. Donchev, M. Schütze: Cyclic oxidation behaviour of halogen implanted Ti-46.5Al-4(Cr, Nb, Ta, B); Materials Science Forum 461-464 (2004) 447-454
A. Donchev, M. Schütze: Gib Sauerstoff bei Leichtmetallen keine Chance; in "Trendbarometer Technik", H.-J. Bullinger (Ed.), Hanser Verlag. Berlin (2004) 148-149
A. Donchev, M. Schütze: Hochtemperatur Oxidationsschutz für intermetallische Titanaluminidleichtbaulegierungen durch Nutzung des Halogeneffekts; Proc. Oberflächentage 2004, Deutsche Gesellschaft für Galvano- und Oberflächentechnik e.V. (DGO, Düsseldorf (2004) 93-99
A. Donchev, M. Schütze: Oxidationsschutz durch Halogene; Metalloberfläche 58 (2004) 32-34
A. Donchev, H.-E. Zschau, M. Schütze: The astounding effect of halogens improving the oxidation resistance of titanium aluminide light weight materials; in "Trends in Electrochemistry and Corrosion at the Beginning of the 21st Century", Eds. E. Brilas, P.-L. Cabot, Publ. Universitat de Barcelona (2004) 1097-1123
H.-E. Zschau, M. Schütze, H. Baumann, K. Bethge: Application of ion beam analysis for the control of the improvement of the oxidation resistance of TiAl at 900 °C in air by fluorine ion implantation an HF-treatment; Nuclear Instruments and Methods in Physics Research B 240 (2005) 137-141
H.-E. Zschau, M. Schütze, H. Baumann, K. Bethge: The Quantitative Role of Surface Doped Fluorine for the Improvement of Oxidation Resistance of TiAl in Air; Materials Science Forum 461-464 (2004) 505-512
A. Donchev, H.-E. Zschau, M. Schütze: The halogen effect for improving the oxidation resistance of TiAl-alloys; Materials at High Temperatures 22 (2005) 309-314
M. Schütze: Recent advances in the understanding of the halogen effect in the oxidation of intermetallic titanium aluminides; in "High temperature corrosion and materials chemistry V: Proceedings of the International Symposium of the Electrochemical Society", Eds. E. Opila, J.W. Fergus, T. Maruyama, J. Mizusaki (2005) 1-15
H.-E. Zschau, M. Schütze: Ein kostensparendes Verfahren zur Verbesserung der Oxidationsbeständigkeit von Gamma-TiAl-Legierungen bei Temperaturen von 800°C bis 1000°C; Metalloberfläche 59 (2005) 1-25
H.-E. Zschau, M. Schütze: Oxidationsschutz durch Fluor - Verbesserung der Oxidationsbeständigkeit von Gamma-TiAl-Legierungen bei Temperaturen von 800 bis 1.000 Grad Celsius; Metalloberfläche 59 (2005) 31-34
A. Donchev, E. Richter, M. Schütze, R. Yankov: Improvement of the Oxidation Behaviour of TiAl-alloys by Treatment with Halogens; Intermetallics 14 (2006) 1168-1174
A. Donchev, M. Schütze: Oxidationsschutz durch Fluorbehandlung; Metalloberfläche 60/12 (2006) 26-28
A. Donchev, M. Schütze, J. Heller, M. Scheydecker: Oxidationsschutz für Titanaluminidbauteile durch Oberflächenbehandlung mit Fluor; Oberflächentage 2006, Proceedings (CD), ZWO, Bonn (2006)
P.J. Masset, A. Donchev, H.-E. Zschau, M. Schütze: Recent developments in the high temperature oxidation protection of TiAl-alloys by using the fluorine effect; Proc. EuroCorr 2006 Part 2 (2006) 587-598
P.J. Masset, H.-E. Zschau, M. Schütze: TiAl oxidation protection improvements using the halogen effect; Proc. 8th Liege Conference. Materials for Advanced Power Engineering, Eds. J. Lecomte-Beckers, M. Carton, F. Schubert, P.J. Ennis, Schriften des Forschungszentrums Jülich 53 (2006) 783-792
P.J. Masset, H.-E. Zschau, M. Schütze: Comparative fluorine surface treatments for TiAl oxidation protection; Ti-2007 Science and Technology, Journal of the Japan Institute of Metals (2007) 1699-1702
R.A. Yankov, A. Kolitsch, A. Rogozin, M. Steinert, A. Donchev, M. Schütze: Oxidation-resistant γ-TiAl alloys produced by ion implantation of fluorine; Proc. E-MRS Spring Symposium, Strasbourg/F (2007)
R.A. Yankov, A. Kolitsch, M. Steinert, A. Donchev, M. Schütze: Oxidation-resistant TiAl alloys produced by plasma immersion ion implantation of fluorine; Proc. 9th Int. Workshop on Plasma Based Ion Implantation & Deposition, Leipzig (2007)
R.A. Yankov, N. Shevchenko, A. Rogozin, M.F. Maitz, E. Richter, W. Möller, A. Donchev, M. Schütze: Reactive plasma immersion ion implantation for surface passivation; Surface & Coatings Technology 201 (2007) 6752-6758
H.-E. Zschau, M. Schütze, H. Baumann, K. Bethge: The time behaviour of surface applied fluorine inducing the formation of an alumina scale on gamma-TiAl during oxidation at 900°C in air; Intermetallics (2006) 1136-1142
S. Neve, H.-E. Zschau, P.J. Masset, M. Schütze, R. Dörner: Kurzzeitoxidation Fluor-implantierter TiAl-Legierungen; Jahresbericht 2007, Institut für Kernphysik, Universität Frankfurt am Main
H.-E. Zschau, M. Schütze: Formation of a protective Alumina Layer by Fluorine Doping of Titanium Aluminide Surfaces; Ti-2007 Science and Technology, Journal of the Japan Institute of Metals (2007) 1695-1698
H.-E. Zschau, M. Schütze, H. Baumann, K. Bethge: Surface modification of titanium aluminides with fluorine to improve their application for high temperature service conditions; Nuclear Instruments and Methods in Physics Research B 257(2007) 383-387
E. Berghof-Hasselbächer, S. Diliberto, P. Gawenda, P.J. Masset, G. Schmidt, M. Schütze: Metallographische Untersuchungen der Mikrostrukturen von technischen TiAl-Legierungen; Sonderbände der Praktischen Metallographie 40 (2008) 117-124
A. Donchev, A. Kolitsch, W. Möller, M. Schütze, R. Yankov: The fluorine effect for high temperature oxidation protection of TiAl-alloys for automotive and aero-engine applications; in "Structural Aluminides for Elevated Temperatures", Eds. Y.-W. Kim, D. Morris, R. Yang, C. Leyens, TMS Warrendale/USA (2008) 323
A. Donchev, E. Richter, M. Schütze, R. Yankov: Improving the Oxidation Resistance of TiAl-Alloys with Fluorine; Journal of Alloys and Compounds 452 (2008) 7
A. Donchev, M. Schütze: Improving the Oxidation Resistance of γ-Titanium Aluminides by Halogen Treatment; Materials and Corrosion 59 (2008) 489-493
A. Donchev, M. Schütze: The use of fluorine for the protection of TiAl-components against high-temperature oxidation; VDI-Berichte 2008, 1st EUCOMAS, VDI Verlag Düsseldorf (2008) 393
P.J. Masset, S. Neve, H.-E. Zschau, M. Schütze: Influence of alloy compositions on the halogen effect in TiAl alloys; Materials and Corrosion 59 (2008) 609-618
P.J. Masset, M. Schütze: Improvement of the oxidation resistance of TiAl alloys using controlled gaseous fluorination; ECS Trans. 11 (2008) 37
P.J. Masset, M. Schütze: Thermodynamic assessment of the alloy concentration limits for the halogen effect of TiAl alloys; Advanced Engineering Materials 10 (2008) 666-674
H.-E. Zschau S. Neve, P.J. Masset, M. Schütze, H. Baumann, K. Bethge: Characterization of the long time oxidation protection of fluorine implanted technical TiAl-alloys using ion beam methods; Nuclear Instruments and Methods in Physics Research B 266 (2008) 2441-2445
H.-E. Zschau, M. Schütze: Modelling of the long time stability of the fluorine effect in TiAl oxidation; Materials and Corrosion 59 (2008) 619-623
H.-E. Zschau, M. Schütze: Multiple F-Implantation for Improved Oxidation Protection of Gamma-TiAl Alloy; Proceedings of the TMS Conference "Structural Aluminides for Elevated Temperature Applications", New Orleans/USA (2008)
A. Donchev, R. Braun, M. Schütze: Fluorine treatment for improved adherence of EB-PVD thermal barrier coatings on TiAl alloys; in TMS 2009 Supplemental Proceedings Vol. 1: Materials Processing and Properties, The Metals and Minerals Society (TMS) Warrendale/USA (2009) 211
A. Donchev, P.J. Masset, M. Schütze: Surface treatment of TiAl with fluorine for improved performance at elevated temperatures; Mater. Res. Soc. Symp. Proc. 1128 (2009) 159
A. Donchev, R. Pflumm, M. Schütze: Application of the fluorine effect to TiAl-components; Materials Research Society Symposium Proceedings 1128 (2009) 209
A. Donchev, M. Schütze, R. Yankov, A. Kolitsch: Plasma-Immersion-Ion-Implantation of Fluorine to Protect TiAl-Components against High Temperature Oxidation; Plasma Processes and Polymers 6/6-7 (2009) 434
P.J. Masset, M. Laurent, M. Schütze: Characterisation of the oxide/metal interface of fluorine treated titanium aluminides; Defect and Diffusion Forum 289-292 (2009) 397-404
E. Wild, W. Reimers, R. Pflumm, M. Schütze: Space-resolved 2D X-ray phase analysis on structured TNB-V5 after oxidation for 24hr at 900°C; Jahresbericht HASYLAB 2008 (2009)
R.A. Yankov, A. Kolitsch, J. Borany, F. Munnik, A. Donchev, M. Schütze: Surface modification of Ti and low Al-content Ti-alloys for enhanced environmental stability at elevated temperatures; E-MRS Spring Meeting 2009, Proceedings (CD)
E. Berghof-Hasselbächer, P. Gawenda, P.J. Masset, G. Schmidt, M. Schütze, S. Diliberto: The Metallographic Investigation of TiAl Technical Alloy Microstructures; Practical Metallography 47 (2010) 65-83
A. Donchev, R. Braun, M. Schütze: Optimizing thermally grown oxide for thermal barrier coatings on TiAl components via fluorine treatment; JOM 62/1 (2010) 70
A. Donchev, M. Schütze: Comparison of different fluorine treatments for the protection of TiAl-alloys against high temperature oxidation; Materials Science Forum 638-642 (2010) 1294
A. Donchev, M. Schütze: Fluorine treatment of TiAl-components for enhancing high-temperature oxidation resistance; EUCOMAS 2010 Proceedings (CD)
A. Donchev, M. Schütze, A. Kolitsch, R. Yankov: Enhanced resistance of Ti-alloys against environmental attack by a combined Al- and F-treatment; TMS 2010 Supplemental Proceedings Vol. 3: Generals Paper Selections, The Metals and Minerals Society (TMS) Warrendale (2010) 119
A. Donchev, M. Schütze, A. Kolitsch, R. Yankov: Improved environmental resistance of Ti-alloys at elevated temperatures by a combined Al- and F-Treatment; Materials Science & Technology MS&T 2010 Proceedings (CD)
A. Donchev, M. Schütze, A. Kolitsch, R. Yankov: Investigation of the F-effect for oxidation protection of 1st, 2nd and 3rd generation TiAl-alloys; MS&T 2010: Proceedings of Materials Science and technology (2010) 2140-2148
A. Donchev, M. Schütze, A. Kolitsch, R. Yankov: Protection of TiAl-components against high temperature oxidation with fluorine; Materials Science & Technology MS&T 2010 Proceedings (CD)
P.J. Masset, M. Schütze: Oxidation tests with untreated and F-treated TNBV5 alloys; ECS Transactions 25 (2010) 45-56
P.J. Masset, R. Yankov, A. Kolitsch, M. Schütze: Comparison of fluorination treatments to improve the high temperature oxidation resistance of TiAl alloys in SO₂ containing environments; Materials Science Forum 638-642 (2010) 1374-1378
S. Neve, P.J. Masset, R.A. Yankov, A. Kolitsch, H.-E. Zschau, M. Schütze: High temperature oxidation resistance of fluorine-treated TiAl alloys: Chemical vs. ion beam fluorination techniques; Nuclear Instruments and Methods in Physics Research B 268/21 (2010) 3381-3385
S. Neve, P.J. Masset, H.-E. Zschau, M. Schütze: Effect of Heating Rate on the Fluorine Content in TiAl-alloy After Oxidation at 900°C; ECS Transactions 25 (2010) 79-86
S. Neve, K. Stiebing, L.P.H. Schmidt, H.-E. Zschau, P.J. Masset, M. Schütze: Non-destructive fluorine depth profiling as quality assurance for the oxidation protection of TiAl turbine blades; Materials Science Forum 638-642 (2010) 1384-1389
A. Donchev, A. Kolitsch, M. Schütze, R. Yankov: Combined Al- plus F-treatment of Ti-alloys for improved behaviour at elevated temperatures; Materials and Corrosion 62 (2011) 695-698
S. Neve, P.J. Masset, H.-E. Zschau, M. Schütze: Measurements of fluorine depth-profiles on TiAl turbine blades using ion beam analytical techniques; Materials and Corrosion 62 (2011) 713-716
R. Pflumm, M. Schütze: Shark-skin inspired surface engineering on intermetallic titanium aluminides for high temperature applications using the fluorine effect; Materials Research Society Symposium Proceedings 1295 (2011) mrsf10-1295-n04-12
H.-E. Zschau, M. Schütze: Oxidation Protection of Titanium Aluminides and Ni-base Superalloys at high Temperatures by the Halogen Effect - Principles and Applications; Proc. ISHOC-10, Zushi, Japan (accepted)

Silicides and Si-based Ceramics

S. Becker, A. Rahmel, M. Schütze: Oxidation of TiSi₂ and MoSi₂; Solid State Ionics 53-56 (1992) 280-289
S. Melsheimer, A. Rahmel, M. Schütze: Mechanismus der Hochtemperaturoxidation von Molybdän- und Titandisilizid; in "Refractory Metals and Hard Materials - Key to Advanced Technologies", Eds. H. Bildstein, R. Eck, Vol. 1, Plansee Metall AG, Reutte (1993) 939
K. Bundschuh, S. Melsheimer, M. Schütze: Hochtemperaturoxidation von MoSi₂ als Beschichtungswerkstoff auf SiC-Keramik; Fortschrittsber. DKG 10 (1995) 182-194
K. Bundschuh, M. Schütze: The Characterisation of the Environmental Resistance of Advanced Materials above 1500ºC; Proc. esa/estec 3rd European Workshop on High Temperature Materials, esa - European Space Agency, Paris (1996) 145-150
K. Bundschuh, M. Schütze, C. Müller, P. Greil, W. Heider: Selection of Materials for Use at Temperatures above 1500°C in Oxidizing Atmospheres; Key Engineering Materials 132-136 (1997) 1564-1567
S. Melsheimer, M. Fietzek, V. Kolarik, A. Rahmel, M. Schütze: Oxidation of the Intermetallics MoSi₂ and TiSi₂- A Comparison; Oxidation of Metals 47 (1997) 139-203
S. Melsheimer, A. Rahmel, M. Schütze: Changes in the Transport Properties of Silicon Dioxide Due to Doping of Foreign Ions; Oxidation of Metals 47 (1997) 205-213
M. Schütze, M. Hald, C. Lang. S. Melsheimer, A. Rahmel: Intermetallic disilicides and titanium aluminides - a new class of structural high temperature materials under the aspect of their high temperature oxidation resistance; Pure & Appl. Chem. 69 (1997) 2335-2341
K. Bundschuh, M. Schütze, C. Müller, P. Greil, W. Heider: Selection of Materials for Use at Temperatures Above 1500°C in Oxidizing Atmospheres; Journal of the European Ceramic Society 18 (1998) 2389-2391
S. Lohfeld, F. Dettenwanger, M. Schütze, R. Rix, V. Güther, R. Scholl: Influence of Second Phase Particles on the Oxidation Behaviour of MoSi₂ at 1600°C in Air; in "Solution of Corrosion Problems in Advanced Technologies", Eds. G. Schmitt, M. Schütze, Chapter 2/29, DECHEMA, Frankfurt am Main 1999
S. Lohfeld, F. Dettenwanger, M. Schütze, K. Bundschuh, R. Rix, V. Güther, R. Scholl: Investigation of the Oxidation Behaviour of Selected MoSi₂ Based Composites at High Temperatures; Proc. Eurocorr 2000 (CD), London
K. Bundschuh, M. Schütze: Materials for Temperatures above 1500°C in Oxidizing Atmospheres Part I: Basic Considerations on Materials Selection; Materials and Corrosion 52 (2001) 204-212
K. Bundschuh, M. Schütze: Materials for Temperatures above 1500°C in Oxidizing Atmospheres Part II: Experimental Results on the Oxidation of MoSi₂ Composites and Coated RSiC; Materials and Corrosion 52 (2001) 268-282
K. Bundschuh, M. Schütze: Materials for Temperatures above 1500°C in Oxidizing Atmospheres Part III: Contact Reaction Tests; Materials and Corrosion 52 (2001) 351-361
S. Lohfeld, M. Schütze: Oxidation behaviour of particle reinforced MoSi₂ composites at temperatures up to 1700°C - Part I: Literature review; Materials and Corrosion 56 (2005) 93-97
S. Lohfeld, M. Schütze, A. Böhm, V. Güther, R. Rix, R. Scholl: Oxidation behaviour of particle reinforced MoSi₂ composites at up to 1700°C - Part II: Initial screening of the oxidation behaviour of MoSi₂ composites; Materials and Corrosion 56 (2005) 149-158
S. Lohfeld, M. Schütze, A. Böhm, V. Güther, R. Rix, R. Scholl: Oxidation behaviour of particle reinforced MoSi₂ composites at temperatures up to 1700°C - Part III: Oxidation behaviour of optimised MoSi₂ composites; Materials and Corrosion 56 (2005) 250-258

Materials in Water Vapour Containing Enviroments

W. Christl, A. Rahmel, M. Schütze: Behavior of Oxide Scales on 2.25Cr-1Mo Steel During Thermal Cycling. II. Scales Grown in Water Vapor; Oxidation of Metals 31 (1989) 35
A. Zeller, F. Dettenwanger, M. Schütze: Influence of Water Vapor on the Creep Behaviour of TiAl; in "Gamma Titanium Aluminides 1999", Eds. Y.-W. Kim et al., TMS, Warrendale (1999) 761-768
A. Zeller, F. Dettenwanger, M. Schütze: Influence of Water Vapour on the Oxidation Behaviour of TiAl at 700 and 750°C; in "Solution of Corrosion Problems in Advanced Technologies", Eds. G. Schmitt, M. Schütze, Chapter 2/31, DECHEMA, Frankfurt am Main (1999)
F. Dettenwanger, M. Schorr, J. Ellrich, T. Weber, M. Schütze: The Influence of Si, W and Water Vapour on the Oxidation Behaviour of 9Cr Steels; CORROSION 2001, NACE, Houston (2001) 01151/1-8
F. Dettenwanger, M. Schorr, J. Ellrich, T. Weber, M. Schütze: The influence of water vapour and silicon on the long term oxidation behaviour of 9Cr Steels; in "Lifetime modelling of high temperature corrosion processes", Eds. M. Schütze, W.J. Quadakkers, J.R. Nicholls, Maney Publ., London (2001) 206-219
A. Zeller, F. Dettenwanger, M. Schütze: Influence of water vapour on the creep and fatigue properties of TiAl; Intermetallics 10 (2002) 33-57
A. Zeller, F. Dettenwanger, M. Schütze: Influence of water vapour on the oxidation behaviour of titanium aluminides; Intermetallics 10 (2002) 59-72
M. Schütze, D. Renusch, M. Schorr: Parameters determining the breakaway oxidation behaviour of ferritic-martensitic 9% Cr steels in environments containing H₂O; Corrosion engineering, science and technology 39 (2004) 157-166
M. Schütze, M. Schorr, D. Renusch, A. Donchev, J. Vossen: The role of alloy composition, environment and stresses for the oxidation resistance of modern 9% Cr steels for fossil power stations; Materials Research 7 (2004) 111-123
A. Donchev, H. Fietzek, V. Kolarik, D. Renusch, M. Schütze: The effect of water vapor in increasing growth stresses in the oxide scale on martensitic steam plant alloys; Materials at High Temperatures 22 (2005) 139-146
M. Schütze, D. Renusch, M. Schorr: Chemical-mechanical failure of oxide scales on 9% Cr steels in air with H₂O; Materials at High Temperatures 22 (2005) 113-120
D. Renusch, M. Schütze: Experience with the use of the acoustic emission technique for monitoring scalefailure in wet and dry environments; Materials at High Temperatures 22 (2005) 35-45
K. Yanagihara, D. Renusch, M. Röhrig, M. Schütze: Effect of Cr Content and Water Vapor on Fracture Behavior of the Scales Formed on Fe and Fe-Cr Alloy; Materials Science Forum 522-523 (2006) 497
I.G. Wright, M. Schütze, P.F. Tortorelli, R.B. Dooley: Towards improved prediction of scale exfoliation from steam tubes; Materials at High Temperatures 24 (2007) 265-274
B. Iwanschitz, J. Sfeir, A. Mai, M. Schütze: Degradation of SOFC Anodes upon Redox Cycling: A Comparison Between Ni/YSZ and Ni/CGO; Journal of The Electrochemical Society 157 (2010) B269-B278
D. Schmidt, M. Schütze: Improved Corrosion Resistance of Superheater Materials in H2O Containing Environments using Mn-Diffusion Coatings; Materials Science Forum 696 (2011) 330-335

Heat-Resistant Steels

J. Barbehön, A. Rahmel, M. Schütze: Behavior of the Scale on a 9.5Cr Steel under Cyclical Deformation of the Base Metal; Oxidation of Metals 30 (1988) 85
W. Christl, A. Rahmel, M. Schütze: Behavior of Oxide Scales on 2.25Cr-1Mo Steel During Thermal Cycling. I. Scales Formed in Oxygen and Air; Oxidation of Metals 31 (1989) 1
W. Christl, A. Rahmel, M. Schütze: Behavior of Oxide Scales on 2.25Cr-1Mo Steel During Thermal Cycling. II. Scales Grown in Water Vapor; Oxidation of Metals 31 (1989) 35
B. Glaser, M. Schütze, F. Vollhardt: Auswertung von Daten zum H₂S-Angriff auf Stähle bei verschiedenen Temperaturen und Konzentrationen; Chem. Ing. Techn. 63 (1991) 634
M. Schulte, M. Schütze: The Behaviour of Protective Sulfide Scales on Various Steels in H₂S-Containing Atmospheres during Temperature Changes; in "Progress in the Understanding and Prevention of Corrosion", Eds. J.M. Costa, A.D. Mercer, The Institute of Materials, London (1993) 750
M. Walter, M. Schütze, A. Rahmel: Behavior of Oxide Scales on 12Cr-1Mo Steel During Thermal Cycling; Oxidation of Metals 39 (1993) 389-410
M. Schütze, M. Nöth: The Sulfidation Resistance of Several Fe- and Ni-Base Alloys and of Two Intermetallics in Atmospheres Containing H₂S at 400-700ºC; Proc. 13th ICC, Australasian Corrosion Association, Melbourne (1996) 1534-1542
J.P.T. Vossen, M. Schütze: Isothermal and Thermocyclic Oxidation Behaviour of Heat-resistant Chromium Containing Steels in Air at 650ºC; Proc. EUROCORR '96, Vol. III, Paper OR 11 Centre Français de l'Anticorrosion/Société de Chimie Industrielle, Paris 1996
J.P.T. Vossen, M. Schütze: Limits for the Recovery of Chromium Oxide Scales on Heat-resistant Stainless Steels in Air With and Without Superimposed Mechanical Load at 650°C; Proc. Int. Conf. Corrosion-Deformation Interactions (CDI), Vol. IV, Paper P 40 Centre Français de l'Anticorrosion/Société de Chimie Industrielle, Paris 1996
J.P.T. Vossen, P. Gawenda, K. Rahts, M. Röhrig, M. Schorr, M. Schütze: Limits of the Oxidation Resistance of Several Heat-resistant Steels under Isothermal and Cyclic Oxidation as well as under Creep in Air at 650°C; Materials at High Temperatures 14 (1997) 387-401
M. Schulte, A. Rahmel, M. Schütze: The Sulfidation Behavior of Several Commercial Ferritic and Austenitic Steels; Oxidation of Metals 49 (1998) 33-70
M. Schulte, M. Schütze: The Role of Scale Stresses in the Sulfidation of Steels; Oxidation of Metals 51 (1999) 55-77
F. Dettenwanger, M. Schorr, J. Ellrich, T. Weber, M. Schütze: The Influence of Si, W and Water Vapour on the Oxidation Behaviour of 9Cr Steels; CORROSION 2001, NACE, Houston (2001) 01151/1-8
F. Dettenwanger, M. Schorr, J. Ellrich, T. Weber, M. Schütze: The influence of water vapour and silicon on the long term oxidation behaviour of 9Cr Steels; in "Lifetime modelling of high temperature corrosion processes", Eds. M. Schütze, W.J. Quadakkers, J.R. Nicholls, Maney Publ., London (2001) 206-219
M. Schütze, D. Renusch, M. Schorr: Parameters determining the breakaway oxidation behaviour of ferritic-martensitic 9% Cr steels in environments containing H₂O; Corrosion engineering, science and technology 39 (2004) 157-166
M. Schütze, M. Schorr, D. Renusch, A. Donchev, J. Vossen: The role of alloy composition, environment and stresses for the oxidation resistance of modern 9% Cr steels for fossil power stations; Materials Research 7 (2004) 111-123
G. Wright, M. Schütze, S.R. Paterson, P.F. Tortorelli, R.B. Dooley: Progress in prediction and control of scale exfoliation on superheater and reheater alloys; Proc. EPRI International Conference on Boiler Tube and HRSG Tube Failures and Inspections, San Diego (2004)
A. Donchev, H. Fietzek, V. Kolarik, D. Renusch, M. Schütze: The effect of water vapor in increasing growth stresses in the oxide scale on martensitic steam plant alloys; Materials at High Temperatures 22 (2005) 139-146
M. Schütze, D. Renusch, M. Schorr: Chemical-mechanical failure of oxide scales on 9% Cr steels in air with H₂O; Materials at High Temperatures 22 (2005) 113-120
M. Schütze, E. Berghof-Hasselbächer, J.J. Hoffman: Development of an atlas of microstructures for the latest heat-resistant cast alloys; NACE Corrosion 2007, Paper 07425/1-11
E. Berghof-Hasselbächer, P. Gawenda, M. Schorr, M. Schütze, J.J. Hoffman: Atlas of Microstructures; Materials Technology Institute, St. Louis (2008)
E. Berghof-Hasselbächer, M. Schorr, P. Gawenda, M. Schütze, J.J. Hoffman: The Development of a Microstructural Atlas of the Latest Heat Resistant Centrifugal Casting Alloys; Practical Metallography 45 (2008) 441-454
J. Kalivodová, D. Baxter, M. Schütze: Corrosion behaviour of boiler steels, coatings and welds in flue gas environments; Materials and Corrosion 59 (2008) 367-373
G. Kunschert, H.-P. Martinz, M. Schütze: Investigation of Oxide-Nucleation on ferritic FeCr Interconnect Alloys for Solid Oxide Fuel Cells exposed to Anode and Cathode Gases at 850°C; Materials Science Forum 559-598 (2008) 779-787
V. Vokál, V. Rohr, M.J. Pomeroy, M. Schütze: Corrosion of alloys and their diffusion aluminide coatings by KCl:K2SO₄ deposits at 650°C in air; Materials and Corrosion 59 (2008) 374-379

Investigation Techniques

K.-H. Döhle, A. Rahmel, M. Schmidt, M. Schütze: Two Different Test Rigs for Creep Experiments in Aggressive Environments; in "Corrosion and Mechanical Stress at High Temperatures", Eds. V. Guttmann, M. Merz, Applied Science Publishers, London (1981) 441
J. Barbehön, K.-H. Döhle, M. Schütze: Acquisition of Experimental Data with the Aid of a Personal Computer during Long-Term Experiments in a Laboratory Testing High Temperature Materials; Computer Applications in the Laboratory 5 (1984) 336
U. Bruch, K. Döhle, J. Pütz, A. Rahmel, M. Schütze, K.D. Schuhmacher: Comparison of the Corrosion Behaviour of Different High Temperature Alloys with and without Superimposed Creep Deformation in an Artificial Steam Reformer Atmosphere; in "Metallic Corrosion 1984", Vol. III, National Research Council Canada, Toronto (1984) 325
M. Schütze, J. Barbehön, K.-H. Döhle: Automatisierte Meßdatenerfassung mit Hilfe des Personalcomputers bei der Ermittlung von Hochtemperatur-Festigkeitskennwerten; in "Werkstoffprüfung 1984", DVM, Berlin (1985) 167
W. Christl, A. Rahmel, M. Schütze: Application of the Acoustic Emission Technique for the Detection of Oxide Scale Cracking during Thermal Cycling; Materials Science and Engineering 87 (1987) 289-293
M. Schütze, K. Döhle, H. Fellmann: Untersuchung und Bewertung des Verhaltens von Hochtemperaturwerkstoffen unter gleichzeitiger thermisch-chemisch-mechanischer Belastung; in "Werkstoffprüfung 1987", DVM, Berlin (1987) 23
R. Luger, B. Genswürger-Geerißen, F. Petri, D. Puppel, M. Schütze: Transmissionselektronenmikroskopische Untersuchungen zum Ausscheidungsverhalten von CuNi10(Fe)-Legierungen; Z. Metallkunde 79 (1988) 259
M. Schütze: Ein auf dem Verständnis der Mechanismen basierendes Konzept zur Prüfung der Hochtemperaturkorrosionsbeständigkeit unter mechanischer Beanspruchung; in "Werkstoffprüfung 1988", DVM, Berlin (1988) 419
L. Hodulak, M. Schütze: Rechnerprogramm für PC zum Nachweis der Tolerierbarkeit von Fehlern für Komponenten des chemischen Apparatebaus; Mat.-wiss. u. Werkstofftech. 20 (1989) 236
B. Glaser, K. Rahts, M. Schorr, M. Schütze: Nachweis von Chloriden in metallischen Werkstoffen bei Hochtemperaturkorrosion; Sonderbände der Praktischen Metallographie 25 (1994) 75-84
S.R.J. Saunders, M.M. Nagl, M. Schütze: Measurement Methods for the Determination of Fracture Strain; Mater. High Temp. 12 (1994) 103-109
M. Schütze: Hochtemperaturkorrosion und mechanische Beanspruchung; in "Korrosion verstehen - Korrosionsschäden vermeiden", Eds. H. Gräfen, A. Rahmel, Verlag Irene Kuron, Bonn (1994) 402-410
K. Rahts, M. Schorr, M. Schütze, M. Schmitz-Niederau: Darstellung von Oxidschichten und Gefüge von TiAl-Legierungen aus Hochtemperaturversuchen; Practical Metallography 27 (1995) 561-565
C. Lang, M. Schütze: TEM Investigations of the Early Stages of TiAl Oxidation; Oxidation of Metals 46 (1996) 255-285
C. Bruns, M. Schütze: Messung der Haftfestigkeit von Deckschichten mittels Schallemissionsanalyse; Berichtsband 58 "Statusberichte zur Entwicklung und Anwendung der Schallemissionsanalyse", Deutsche Gesellschaft für Zerstörungsfreie Prüfung e.V. Berlin (1997) 235-237
K. Rahts, M. Nöth, M. Schulte, M. Schorr, P. Gawenda, M. Schütze: Untersuchungen an Sulfidschichten verschiedener Hochtemperaturwerkstoffe aus thermischer Beanspruchung in H₂S-haltiger Atmosphäre; Sonderbände der Praktischen Metallographie 28 (1997) 229-236
M. Schütze, C. Bruns: Stresses and Adhesion of Surface Scales; in "Corrosion-Deformation Interactions", Ed. T. Magnin, EFC-Publ. No. 21, The Institute of Materials, London (1997) 308-318
K. Rahts, M. Schorr, C. Schwalm, M. Schütze: Untersuchungen über den Einfluß von Chlor bei der Hochtemperaturoxidation; Practical Metallography 29 (1998) 305-311
F. Dettenwanger, H. Echsler, C. Bruns, M. Schütze: Investigation of Damage Mechanisms in Thermal Barrier Coatings by Acoustic Emission; in "Elevated Temperature Coatings: Science and Technology III", Eds. J.M. Hampikian, N.B. Dahotre, TMS, Warrendale (1999)
K. Rahts, M. Schorr, C. Schwalm, M. Schütze: Wasserfreie Präparationsmethode zum Nachweis von Chloriden bei der Hochtemperaturoxidation in chlorhaltigen Atmosphären; Practical Metallography 36 (1999) 86-97
G. Schumacher, F. Dettenwanger, M. Schütze, J.D. Sunderkötter, M.F. Stroosnijder: TEM-Investigations of Oxidized Y-implanted PM Chromium; in "Solution of Corrosion Problems in Advanced Technologies", Eds. G. Schmitt, M. Schütze, Chapter 2/30, DECHEMA, Frankfurt am Main (1999)
E. Berghof-Hasselbächer, M. Schütze: Ein alternatives Schliffpräparationsverfahren zur Verbesserung der optischen Darstellung und Differenzierung nichtmetallischer Schichten gegenüber dem Einbettmittel; Sonderbände der Praktischen Metallographie 31 (2000) 319-325
G. Schumacher, F. Dettwanger, M. Schütze, A. Iberl, D. Reil: XRD Investigations of the Phosphorus Effect on the Oxidation of TiAl Alloys by High-Resolution Methods; Oxidation of Metals 54 (2000) 317-337
C. Bruns, M. Schütze: Investigation of the Mechanical Properties of Oxide Scales on Nickel and TiAl; Oxidation of Metals 55 (2001) 35-68
M. Schütze, S. Ito, W. Przybilla, H. Echsler, C. Bruns: Test Methods and Data on the Mechanical Properties of Protective Oxide Scales; Materials at High Temperatures 18 (2001) 39-50
E. Berghof-Hasselbächer, H.-E. Bühler, O. Greven, M. Schorr, J. Schürhoff, M. Schütze: Untersuchungen zum Bauteilversagen von Rostsystemen bei der Restholzverbrennung; Practical Metallography 39 (2002) 369-386
E. Berghof-Hasselbächer, C. Rosado Sainz-Rosas, M. Schütze: Korrosionsschutzschichten gegen Metal Dusting Angriff; Sonderbände der Praktischen Metallographie 34, Ed. G. Petzow, Werkstoff-Informationsgesellschaft, Frankfurt am Main (2002) 271-281
E. Berghof-Hasselbächer, C. Rosado Sainz-Rozas, M. Schütze: Protective Coatings to Prevent Metal Dusting; Practical Metallography 40 (2003) 407-419
E. Berghof-Hasselbächer, A. Littner, M. Schütze, M. Schorr, P. Gawenda: Charakterisierung von Al- und PtAl-Diffusionsbeschichtungen auf Ni-Basis-Superlegierungen; Sonderbände der Praktischen Metallographie 35 (2004) 325-336
E. Berghof-Hasselbächer, E. Nicolas, V. Rohr, M. Schütze: Bildanalytische Schichtdickenbestimmung an Al-Diffusionsbeschichtungen; Sonderbände der praktischen Metallographie 36 (2004) 451-457
E. Berghof-Hasselbächer, M. Schorr, P. Gawenda, M. Schütze: Potentiale und Grenzen der Interferenzschichten-Metallographie bei der Charakterisierung von Karbidtypen am Beispiel hitzebeständiger Schleudergusswerkstoffe; Sonderbände der praktischen Metallographie 37 (2005) 173-179
D. Renusch, M. Schütze: Experience with the use of the acoustic emission technique for monitoring scale failure in wet and dry environments; Materials at High Temperatures 22 (2005) 33-45
E. Berghof-Hasselbächer, V. Rohr, E. Nicolas, M. Schütze: The determination of Al-diffusion layer thickness by image processing; Practical Metallography 43 (2006) 127-142
B. Isecke, M. Schütze, H.-H. Strehblow: Measurement methods for materials performance - corrosion; Springer Handbook of Materials Measurement Methods, Eds. H. Czichos, T. Saito, L. Smith, Springer-Verlag (2006) 611-684
M. Schütze, M. Malessa: Reliable assessment of high temperature oxidation resistance by the development of a comprehensive code of practice for thermocycling oxidation testing - European COTEST project; Materials and Corrosion 57 (2006) 5-13
E. Berghof-Hasselbächer, M. Schorr, P. Gawenda, M. Schütze, J.J. Hoffman: Entwicklung eines Mikrostrukturatlanten für die neuesten hitzebeständigen Schleudergusswerkstoffe; Sonderbände der Praktischen Metallographie 39 (2007) 81-88
M. Schütze, E. Berghof-Hasselbächer, J.J. Hoffman: Development of an atlas of microstructures for the latest heat-resistant cast alloys; NACE Corrosion 2007, Paper 07425/1-11
E. Berghof-Hasselbächer, S. Diliberto, P. Gawenda, P.J. Masset, G. Schmidt, M. Schütze: Metallographische Untersuchungen der Mikrostrukturen von technischen TiAl-Legierungen; Sonderbände der praktischen Metallographie 40 (2008) 117-124
E. Berghof-Hasselbächer, P. Gawenda, M. Schorr, M. Schütze, J.J. Hoffman: Atlas of Microstructures; Materials Technology Institute, St. Louis (2008)
E. Berghof-Hasselbächer, M. Schorr, P. Gawenda, M. Schütze, J.J. Hoffman: Entwicklung eines Mikrostrukturatlanten für die neuesten hitzebeständigen Schleudergusswerkstoffe; Practical Metallography 45 (2008) 441-454
E. Berghof-Hasselbächer, P.J. Masset, D. Texier, G. Schmidt, P. Gawenda, M. Jusek, M. Schütze: Mikrostrukturen von NiAl_(1-x)Hf_(x)-Legierungen (x=0…0,2); Sonderbände der Praktischen Metallographie 41 (2009) 113-119
I. Teliban, C. Thede, S. Chemnitz, C. Bechtold, W.J. Quadakkers, M. Schütze, E. Quandt: Magnetic moment investigation by frequency mixing techniques; Review of Scientific Instruments 80 (2009) 115106
E. Berghof-Hasselbächer, P. Gawenda, P.J. Masset, G. Schmidt, M. Schütze, S. Diliberto: Metallographische Untersuchungen der Mikrostrukturen von technischen TiAl-Legierungen; Practical Metallography 47 (2010) 65-83
B. Isecke, M. Schütze, H.-H. Strehblow: Measurement methods for materials performance - corrosion; Springer Handbook of Materials Measurement Methods, 2nd Edition, Eds. H. Czichos, T. Saito, L. Smith, Springer-Verlag (2011) 611-684

Corrosion and Protection in Liquid Media

K.H. Büttgen, D. da Silva Rosa, B. du Bois, P. Gawenda, A. Rahmel, K. Rahts, M. Schütze: Stimulation of aqueous corrosion by MoS2 deposits; Materials and Corrosion 49 (1998) 505-511
T. Hollstein, T. Graas, K. Bundschuh, M. Schütze: Das Korrosionsverhalten unterschiedlicher Siliciumnitride in wäßrigen Lösungen; Keramische Zeitschrift 50 (1998) 416-421
H.-Q. Nguyen, W. Fürbeth, M. Schütze: Nano-enamel: a new way to produce glass-like protective coatings for metals; Materials and Corrosion 53 (2002) 772-782
S. Benfer, W. Fürbeth, M. Schütze: Nanopartikelbasierte Schichten für die Emailreparatur; CAV Chemie-Anlagen + Verfahren (5/2006) 44-46
F. Feil, W. Fürbeth, M.Schütze: Kleine Teilchen auf leichtem Metall - Nanopartikel-basierte anorganische Schutzschichten für Magnesiumwerkstoffe; Metalloberfläche 60 (11) (2006) 38-41
F. Feil, W. Fürbeth, M.Schütze: Nanopartikel-basierte anorganische Schutzschichten für Magnesiumwerkstoffe; Tagungsband Oberflächentage 2006 (CD), Bonn (2006)

Role of Microstructure

B. Reppich, H. Bügler, R. Leistner, M. Schütze: Application of the Microstructural Concept of Creep and Rupture Life Time to a γ'-Precipitating Ni-Base Alloy I. Yielding and Creep Behaviour; in "Creep and Fracture of Engineering Materials and Structures", Eds. B. Wilshire, D. Owen, Pineridge Press, Swansea (1984) 279
R. Luger, B. Genswürger-Geerißen, F. Petri, D. Puppel, M. Schütze: Transmissionselektronenmikroskopische Untersuchungen zum Ausscheidungsverhalten von CuNi10(Fe)-Legierungen; Z. Metallkunde 79 (1988) 259
R. Luger, M. Schütze: Einfluß des Fe-Gehalts und der Auslagerungszeit auf mechanische, elektrische und magnetische Eigenschaften der Legierung CuNi10(Fe); Mat.-wiss. u. Werkstofftech. 20 (1989) 60
G. Luxenburger, M. Schütze: Einfluß der Carbidstruktur auf das Kriechverhalten der hitzebeständigen Edelstahl-Gußlegierung HK40; Z. Metallkunde 82 (1991) 430
G. Schumacher, F. Dettenwanger, M. Schütze, J.D. Sunderkötter, M.F. Stroosnijder: TEM-Investigations of Oxidized Y-implanted PM Chromium; in "Solution of Corrosion Problems in Advanced Technologies", Eds. G. Schmitt, M. Schütze, Chapter 2/30, DECHEMA, Frankfurt am Main (1999)
E. Berghof-Hasselbächer, P. Gawenda, M. Schorr, M. Schütze, J.J. Hoffman: Atlas of Microstructures; Materials Technology Institute, St. Louis (2008)
H. Latreche, G. Bozzolo, P.J. Masset, T. Weber, M. Schütze: Measurements of the coefficient of thermal expansion (CTE) of NiAlMo alloys and comparison with modelling predictions; Materials Science and Engineering: A 527/21-22 (2010) 5837
E. Berghof-Hasselbächer, P.J. Masset, L. Zhang, L. Liu, Z. Jin, G. Schmidt, M. Galetz, M. Schütze: Mikrostrukturen von Erbium-modifizierten Aluminium-Kupfer-Legierungen; Sonderbände der Praktischen Metallographie 43 (2011) in press

Mechanical High Temperature Properties without Corrosion

B. Reppich, H. Bügler, R. Leistner, M. Schütze: Application of the Microstructural Concept of Creep and Rupture Life Time to a γ'-Precipitating Ni-Base Alloy I. Yielding and Creep Behaviour; in "Creep and Fracture of Engineering Materials and Structures", Eds. B. Wilshire, D. Owen, Pineridge Press, Swansea (1984) 279
L. Hodulak, M. Schütze: Rechnerprogramm für PC zum Nachweis der Tolerierbarkeit von Fehlern für Komponenten des chemischen Apparatebaus; Mat.-wiss. u. Werkstofftech. 20 (1989) 236
G. Luxenburger, M. Schütze: Einfluß der Carbidstruktur auf das Kriechverhalten der hitzebeständigen Edelstahl-Gußlegierung HK40; Z. Metallkunde 82 (1991) 430
K. Rüdinger, M. Schütze: Beitrag zum Zeitstandverhalten von Titan für die Anwendung im chemischen Apparatebau; Mat.-wiss. u. Werkstofftechn. 22 (1991) 1

Nanotechnology

W. Fürbeth, H.-Q. Nguyen, F. Dettenwanger, M. Schütze: Development of new corrosion resistant coatings for light metals by sintering of nanopowders; Proc. Eurocorr 2000 (CD), London
W. Fürbeth, H.-Q. Nguyen, F. Dettenwanger, M. Schütze: New developments for corrosion resistant coatings for light metals and steel based on chemical nanotechnology; Proc. EUROCORR 2001 (CD) Associazione Italiana di Metallurgia, Milano (2001)
H.-Q. Nguyen, W. Fürbeth, M. Schütze: Nano-enamel: a new way to produce glass-like protective coatings for metals; Materials and Corrosion 53 (2002) 772-782
W. Fürbeth, H.-Q. Nguyen, M. Schütze: Development of new corrosion resistant coatings based on chemical nanotechnology; Proc. Int. Symposium "Corrosion Science in the 21st century", UMIST, Manchester (2003) (CD), The Journal of Corrosion Science and Engineering, Vol. 6 (2003)
W. Fürbeth, H.-Q. Nguyen, M. Schütze: Nanoenamel - new technologies for functional coatings; ACHEMA-Magazine/ Special edition of Process, Vogel Verlag (2003) 74-75
W. Fürbeth, H.-Q. Nguyen, M. Schütze: Nanopulver-Schichten als Korrosionsschutz für Leichtmetallegierungen; Tagungsband 1. KKF-Kolloquium Gemeinsame Forschung im Korrosionsschutz - Problemlösungen für den metallischen Leichtbau, January 2003, GfKORR e.V., Frankfurt (2003)
W. Fürbeth, H.-Q. Nguyen, M. Schütze: Neue Korrosionsschutzschichten für Metalle auf der Basis chemischer Nanotechnologie; Proc. Oberflächentage 2003, DGO, Düsseldorf (2003)
W. Fürbeth, H.-Q. Nguyen, M. Schütze: Kleine Ursache mit großer Wirkung: Neue Korrosionsschutzschichten für Metalle auf Basis chemischer Nanotechnologie; Metalloberfläche 58 (2004) 31-36
S. Benfer, W. Fürbeth, M. Schütze: Emailreparatur mit nanopartikulären Schichten; Mitteilungen des Deutschen Emailverbandes e.V. 53/5 (2005) 74-83
S. Benfer, W. Fürbeth, M. Schütze: Entwicklung von nanopartikelbasierten Schichten für die Emailreparatur; Tagungsband 6. Industriefachtagung Oberflächen- und Wärmebehandlungstechnik & 8. Werkstofftechnisches Kolloquium, Chemnitz (2005)
W. Fürbeth, S. Benfer, M. Schütze: Repair of technical enamels through nanotechnology; Proc. EUROCORR 2005, Lissabon (2005)
W. Fürbeth, H.-Q. Nguyen. M. Schütze: Nanopartikelbasierte Korrosionsschutzschichten für Leichtmetalle; Tagungsband Thüringer Grenz- und Oberflächentage, Jena (2005)
W. Fürbeth, H.-Q. Nguyen, M. Schütze: Neuartige Korrosionsschutzschichten für Metalle auf der Basis oxidischer Nanopartikel; Tagungsband 6. Wörlitzer Workshop Funktionelle Schichten, Europäische Forschungsgesellschaft Dünne Schichten e.V., Dresden (2005)
W. Fürbeth, M. Schütze: Novel corrosion protective coatings based on nanomaterials; Report Nato-RTO Specialist Meeting AVT-122 Nanomaterials Technology for Military Vehicle Structural Applications, Granada (2005)
S. Benfer, W. Fürbeth, M. Schütze: Email vor Ort reparieren; cav - Chemie-Anlagen + Verfahren (2006) (5) 44-46
F. Feil, W. Fürbeth, M.Schütze: Kleine Teilchen auf leichtem Metall - Nanopartikel-basierte anorganische Schutzschichten für Magnesiumwerkstoffe; Metalloberfläche 60 (11) (2006) 38-41
F. Feil, W. Fürbeth, M.Schütze: Nanopartikel-basierte anorganische Schutzschichten für Magnesiumwerkstoffe; Tagungsband Oberflächentage, Bonn (2006)

Reviews

M. Schütze: Fundamentals of High Temperature Corrosion; in "Corrosion and Environmental Degradation", Eds. R.W. Cahn et al., Wiley-VCH (2000) 67-130
W. Fürbeth, M. Schütze: Progress in corrosion protection as a requirement for technical progress; Materials and Corrosion 60 (2009) 481-494
M. Schütze: Konzepte für die Entwicklung von Schutzschichten für aggressive Hochtemperaturumgebungen; in "Dampferzeugerkorrosion", Saxonia Standortentwicklungs- und -verwaltungsgesellschaft mbH, Freiberg/Sachsen (2009) 169-188
M. Schütze, W. Fürbeth: Innovative Entwicklungen im Bereich Korrosionsschutz von Metallen; Tagungsband 5. Thüringer Grenz- und Oberflächentage, Innovent e.V., Jena (2009) 65-73

Books

M. Schütze: Die Korrosionsschutzwirkung oxidischer Deckschichten unter thermisch-chemisch-mechanischer Werkstoffbeanspruchung; Materialkundlich-Technische Reihe, Vol. 10, Eds. G. Petzow, F. Jeglitsch, Gebr. Borntraeger Verlag, Berlin 1991
H.J. Grabke, M. Schütze (Eds.): Oxidation of Intermetallics; Wiley-VCH, Weinheim 1997
M. Schütze: Protective Oxide Scales and Their Breakdown; Series on Corrosion and Protection, Vol. 1, Ed. D.R. Holmes, John Wiley and Sons, Chichester 1997
M. Schütze, W.J. Quadakkers (Eds.): Cyclic Oxidation of High Temperature Materials; The Institute of Materials, London 1999
G. Schmitt, M. Schütze (Eds.): Solution of Corrosion Problems in Advanced Technologies; DECHEMA, Frankfurt am Main 1999
M. Schütze (Ed.): Corrosion and Environmental Degradation; Vol. 19 of "Materials Science and Technology", Series Eds. R.W. Cahn et al., Wiley-VCH, Weinheim 2000
M. Schütze, W.J. Quadakkers, J.R. Nicholls (Eds.): Lifetime Modelling of High Temperature Corrosion Processes; Maney Publishing, London 2001
G. Kreysa, M. Schütze (Eds.): Corrosion Handbook, Vol. 1: Sodium Hydroxide, Mixed Acids; DECHEMA e.V., WILEY-VCH, Frankfurt am Main and Weinheim 2005
G. Kreysa, M. Schütze (Eds.): Corrosion Handbook, Vol. 2: Hydrochloric Acid, Nitric Acid; DECHEMA e.V., WILEY-VCH, Frankfurt am Main and Weinheim 2005
G. Kreysa, M. Schütze (Eds.): Corrosion Handbook, Vol. 3: Hypochlorites, Phosphoric Acid; DECHEMA e.V., WILEY-VCH, Frankfurt am Main and Weinheim 2005
G. Kreysa, M. Schütze (Eds.): Corrosion Handbook, Vol. 4: Drinking Water, Waste Water (Municipal), Waste Water (Industrial); DECHEMA e.V., WILEY-VCH, Frankfurt am Main and Weinheim 2005
G. Kreysa, M. Schütze (Eds.): Corrosion Handbook, Vol. 5: Carbonic Acid, Chlorine Dioxide, Seawater; DECHEMA e.V., WILEY-VCH, Frankfurt am Main and Weinheim 2005
G. Kreysa, M. Schütze (Eds.): Corrosion Handbook, Vol. 6: Atmosphere, Industrial Waste Gases; DECHEMA e.V., WILEY-VCH, Frankfurt am Main and Weinheim 2006
G. Kreysa, M. Schütze (Eds.): Corrosion Handbook, Vol. 7: Sodium Chloride; DECHEMA e.V., WILEY-VCH, Frankfurt am Main and Weinheim 2006
H.J. Grabke, M. Schütze (Eds.): Corrosion by carbon and nitrogen: Metal dusting, carburisation and nitridation; Woodhead Publishing, Cambridge 2007
G. Kreysa, M. Schütze (Eds.): Corrosion Handbook, Vol. 8, Part A: Chlorinated Hydrocarbons - Chloromethanes; DECHEMA e.V., WILEY-VCH, Frankfurt am Main and Weinheim 2007
G. Kreysa, M. Schütze (Eds.): Corrosion Handbook, Vol. 8, Part B: Chlorinated Hydrocarbons - Chloroethanes, Alkanols; DECHEMA e.V., WILEY-VCH, Frankfurt am Main and Weinheim 2007
G. Kreysa, M. Schütze (Eds.): Corrosion Handbook, Vol. 9: Potassium Hydroxide, Ammonium and Ammonium Hydroxide; DECHEMA e.V., WILEY-VCH, Frankfurt am Main and Weinheim 2007
M. Schütze, M. Malessa (Eds.): Standardisation of thermal cycling exposure testing; Woodhead Publishing, Cambridge 2007
E. Berghof-Hasselbächer, P. Gawenda, M. Schorr, M. Schütze, J.J. Hoffman: Atlas of Microstructures; Materials Technology Institute, St. Louis 2008
G. Kreysa, M. Schütze (Eds.): Corrosion Handbook, Vol. 10: Sulfur Dioxide, Sodium Sulfate; DECHEMA e.V., WILEY-VCH, Frankfurt am Main and Weinheim 2008
G. Kreysa, M. Schütze (Eds.): Corrosion Handbook, Vol. 11: Sulfuric Acid; DECHEMA e.V., WILEY-VCH, Frankfurt am Main and Weinheim 2008
M. Schütze, W.J. Quadakkers (Eds.): Novel approaches to improving high temperature corrosion resistance; EFC no. 47, Woodhead, Cambridge 2008
G. Kreysa, M. Schütze (Eds.): Corrosion Handbook, Vol. 12: Ferrous Chlorides; DECHEMA e.V., WILEY-VCH, Frankfurt am Main and Weinheim 2009

Contributions to Newspapers

C. Hirche, M. Schütze: Werkstoffinnovationen öffnen den Weg zu hochleistungsfähigen neuen Produkten; Frankfurter Allgemeine Zeitung, 7. December 1992
P.P. Schepp, M. Schütze: Messen, Tagungen, Veranstaltungen - auf den Erfahrungsaustausch kommt es bei Werkstoffen an; Frankfurter Allgemeine Zeitung, 25. January 1993
M. Schütze: Hitze läßt neue Werkstoffe kalt; Chemische Industrie 10 (1993) 38-40
M. Schütze: Aus dem Weltraum auf die Erde geholt; Chemische Industrie 12 (1995) 39-40
M. Schütze: Korrosion in der Hochtemperaturtechnik; Spektrum der Wissenschaft July (1998) 100-108
M. Schütze: Beschichtete Stahlbehälter halten aggressiven Medien stand; Handelsblatt, 21. April 1999
M. Schütze: Korrosion - Vergangenheit, Heute und Zukunft; Chemie Ingenieur Technik 75 (2003) 1534-1538
M. Schütze: Chemiewerkstoffe; Werkstoffe in der Fertigung (2005) 4
M. Schütze: Was Menschen bewegt, die etwas bewegen; CITplus 1/2 (2006) 6